{"id":"W1993033822","doi":"10.1016/j.chroma.2007.09.031","title":"Thermodynamics of hydrophobic interaction chromatography of acetyl amino acid methyl esters","year":2007,"lang":"en","type":"article","venue":"Journal of Chromatography A","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":false,"ca_institutions":"Biotechnology Research Institute","funders":"Trent University","keywords":"Chemistry; Solvophobic; Enthalpy; Adsorption; Chromatography; Hydrophilic interaction chromatography; Entropy (arrow of time); van der Waals force; Matrix (chemical analysis); Hydrophobic effect; Organic chemistry; Thermodynamics; High-performance liquid chromatography; Molecule","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.000790222,0.0004628189,0.00112819,0.0009880153,0.00007916935,0.00002998197,0.0007629658,0.0003979858,0.0004360788],"category_scores_gemma":[0.00005966157,0.0004083683,0.002047466,0.001628541,0.0006629414,0.00038681,0.00008053318,0.0006950086,0.000001961791],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005212586,"about_ca_system_score_gemma":0.00009250008,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002010326,"about_ca_topic_score_gemma":0.000005677714,"domain_scores_codex":[0.9960116,0.00004748148,0.002147815,0.0003149796,0.0009534559,0.0005246502],"domain_scores_gemma":[0.9956053,0.000315362,0.002633182,0.0005975303,0.0005001889,0.0003483637],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004696806,0.0006819245,0.02292118,0.0009313514,0.001296637,0.0000736027,0.0004587434,0.00001963219,0.9717861,0.000294658,0.0001231234,0.0009433269],"study_design_scores_gemma":[0.001575929,0.000346393,0.005320576,0.0008117497,0.0005251301,0.0005236568,0.001771935,0.0001522342,0.9870183,0.0009314176,0.0006225972,0.0004000649],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9839116,0.001363617,0.001484955,0.00003086106,0.0002028319,0.00006569126,0.00002888723,0.00004379591,0.01286772],"genre_scores_gemma":[0.9974214,0.0003324248,0.001963643,0.00003234755,0.000167559,0.000002084573,0.00001137272,0.00005429577,0.00001481581],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01760061,"threshold_uncertainty_score":0.9998368,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008855880597924031,"score_gpt":0.2518710640206573,"score_spread":0.2430151834227333,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}