{"id":"W1993234748","doi":"10.1002/cctc.201402817","title":"A New Role for Sulfenate Anions: Organocatalysis","year":2014,"lang":"en","type":"article","venue":"ChemCatChem","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"","keywords":"Organocatalysis; Halide; Chemistry; Catalysis; Ion; Ether; Medicinal chemistry; Organic chemistry; Enantioselective synthesis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000399275,0.000551976,0.0002635492,0.0001960712,0.0002972911,0.0007108952,0.0006101083,0.0006614453,0.002839227],"category_scores_gemma":[0.0002152078,0.0001751133,0.0002592971,0.0001290015,0.0006855218,0.001191456,0.0006022511,0.0009037985,0.0009202478],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000338572,"about_ca_system_score_gemma":0.0003123805,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001922543,"about_ca_topic_score_gemma":0.0003019748,"domain_scores_codex":[0.9998568,0.00002254545,0.000011298,0.00004423579,0.00003584599,0.00002913369],"domain_scores_gemma":[0.9999114,0.0000183587,0.00001773178,0.00001735894,0.00001616574,0.00001882722],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002663445,0.00007720098,0.0001539225,0.000506594,0.00001922717,0.0002847813,0.0001645742,0.0002128303,0.9450335,0.03074731,0.001515564,0.02101808],"study_design_scores_gemma":[0.00006312544,0.0005397809,0.0001161687,0.0000299128,0.00002217112,0.0004082082,0.00005943538,0.0006563128,0.9075946,0.002441578,0.0880373,0.00003143042],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7104537,0.04218579,0.1571948,0.008148961,0.002699085,0.0003457243,0.0009100173,0.0032517,0.07481022],"genre_scores_gemma":[0.9246637,0.01636665,0.03446867,0.0009530548,0.0003607005,0.0001385505,0.0003335473,0.0002338211,0.02248137],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002839227,"threshold_uncertainty_score":0.009498179,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008670530437866631,"score_gpt":0.2297344114124766,"score_spread":0.2210638809746099,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}