{"id":"W1993259613","doi":"10.1107/s0108768103005196","title":"The 1:1 adduct of triphenylsilanol and 4,4′-bipyridyl, and three pairwise-concomitant triclinic polymorphs of the 4:1 adduct having <i>Z</i>′ = 0.5, 1 and 4","year":2003,"lang":"en","type":"article","venue":"Acta Crystallographica Section B Structural Science","topic":"Crystallography and molecular interactions","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; University of Guelph","funders":"","keywords":"Triclinic crystal system; Silanol; Chemistry; Adduct; Hydrogen bond; Crystallography; Molecule; Stereochemistry; Crystal structure; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["sts"],"consensus_categories":[],"category_scores_codex":[0.000531099,0.0002333481,0.0002650162,0.000182405,0.001084942,0.0001260912,0.000374772,0.0001149141,0.00005093621],"category_scores_gemma":[0.0005481317,0.0001439646,0.0001627184,0.001189482,0.003023961,0.0003227829,0.0001680034,0.0003569907,1.026929e-8],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002276336,"about_ca_system_score_gemma":0.0001026663,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002548153,"about_ca_topic_score_gemma":0.0004507202,"domain_scores_codex":[0.9981566,0.00007870905,0.0004892492,0.0005009007,0.0004145081,0.0003600526],"domain_scores_gemma":[0.9984325,0.0004009306,0.0004207177,0.0004406052,0.00016529,0.0001399188],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"observational","study_design_scores_codex":[0.00005117894,0.00001424014,0.03572795,0.0000370137,0.00004933492,9.919935e-7,0.0002039184,0.000002428725,0.9607714,0.0006859753,0.00002191533,0.002433638],"study_design_scores_gemma":[0.003917947,0.0006113256,0.8037421,0.0003924161,0.0005793606,0.002459809,0.006267599,0.000926811,0.1389596,0.01747792,0.02327204,0.001393065],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.996862,0.001288734,0.00002436329,0.00023703,0.0003081613,0.0001997676,0.00003326083,0.00002936288,0.001017327],"genre_scores_gemma":[0.999314,0.0004180374,0.0001446561,0.00003135228,0.00003117367,0.00001208831,0.000001239497,0.00001245503,0.00003497766],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.8218118,"threshold_uncertainty_score":0.9996892,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008654351896737725,"score_gpt":0.2302945512907345,"score_spread":0.2216401993939968,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}