{"id":"W1993318870","doi":"10.1021/om010235z","title":"Syntheses and Structures of New Luminescent Cyclometalated Palladium(II) and Platinum(II) Complexes:  M(Bab)Cl, M(Br−Bab)Cl (M = Pd(II), Pt(II)), and Pd<sub>3</sub>Cl<sub>4</sub>(Tab)<sub>2</sub> (Bab = 1,3-bis(7-azaindolyl)phenyl, Br−Bab = 1-Bromo-3,5-bis(7-azaindolyl)phenyl, Tab =1,3,5-tris(7-azaindolyl)phenyl)","year":2001,"lang":"en","type":"article","venue":"Organometallics","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":100,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Palladium; Luminescence; Platinum; Benzene; Lone pair; Crystallography; Stereochemistry; Molecule; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","research_integrity"],"consensus_categories":["metaepi_narrow","research_integrity"],"category_scores_codex":[0.002319973,0.004311203,0.005320975,0.002895267,0.00298585,0.001232217,0.002686812,0.002390163,0.0004876325],"category_scores_gemma":[0.002949697,0.004458156,0.0009891496,0.00566548,0.002023207,0.002132567,0.004270355,0.003686227,0.0001008573],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001273184,"about_ca_system_score_gemma":0.001104341,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002282005,"about_ca_topic_score_gemma":0.0006049851,"domain_scores_codex":[0.9811592,0.0008312881,0.004644817,0.004320333,0.003790772,0.005253623],"domain_scores_gemma":[0.9882749,0.002115101,0.001738309,0.003627999,0.001051568,0.003192123],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006652523,0.000955805,0.00572408,0.001744971,0.002539833,0.0003510188,0.005308807,0.0003993093,0.9637182,0.0003345261,0.003343675,0.01491454],"study_design_scores_gemma":[0.008761334,0.001573078,0.0165021,0.001189318,0.001467341,0.001278059,0.001577634,0.004024919,0.9473707,0.0006048841,0.01041462,0.005236026],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.977801,0.01198414,0.0005943172,0.0008078171,0.001466017,0.003749499,0.001083483,0.001778407,0.0007353805],"genre_scores_gemma":[0.9799958,0.01299711,0.001786739,0.0002927852,0.002102526,0.0001725226,0.0006745063,0.001470711,0.0005072284],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0163475,"threshold_uncertainty_score":0.9998046,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01611446395325749,"score_gpt":0.2229729308790228,"score_spread":0.2068584669257653,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}