{"id":"W1993318870","doi":"10.1021/om010235z","title":"Syntheses and Structures of New Luminescent Cyclometalated Palladium(II) and Platinum(II) Complexes:  M(Bab)Cl, M(Br−Bab)Cl (M = Pd(II), Pt(II)), and Pd<sub>3</sub>Cl<sub>4</sub>(Tab)<sub>2</sub> (Bab = 1,3-bis(7-azaindolyl)phenyl, Br−Bab = 1-Bromo-3,5-bis(7-azaindolyl)phenyl, Tab =1,3,5-tris(7-azaindolyl)phenyl)","year":2001,"lang":"en","type":"article","venue":"Organometallics","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":100,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Palladium; Luminescence; Platinum; Benzene; Lone pair; Crystallography; Stereochemistry; Molecule; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001204989,0.000293029,0.0002278855,0.0001886294,0.0001820202,0.0004840447,0.0006424928,0.0003402945,0.001535346],"category_scores_gemma":[0.0002430154,0.0003038774,0.0001465548,0.0001872858,0.0002414802,0.000318725,0.0003376215,0.0004592571,0.0004662726],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007438397,"about_ca_system_score_gemma":0.0003031002,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006844251,"about_ca_topic_score_gemma":0.001248345,"domain_scores_codex":[0.999898,0.00001243894,0.00000904499,0.0000282854,0.00003249752,0.00001974009],"domain_scores_gemma":[0.9998883,0.0000126164,0.00003610478,0.00001441217,0.00001836435,0.00003023373],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001812565,0.00006024649,0.0002848247,0.0002774964,0.00002245528,0.0001093866,0.00007512032,0.0004735494,0.9926879,0.0005782513,0.000160459,0.005088978],"study_design_scores_gemma":[0.00003559094,0.0001671081,0.0005423445,0.000003801993,0.00002530891,0.000172896,0.00001795874,0.0004468592,0.9951987,0.00003752709,0.003345708,0.000006356948],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.977812,0.00346609,0.01285666,0.0001335611,0.00004254951,0.0001857818,0.0004086637,0.0003213836,0.004773357],"genre_scores_gemma":[0.9846599,0.001315288,0.00906757,0.00006607182,0.00000619095,0.0001073367,0.0004669034,0.00003308441,0.004277718],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001535346,"threshold_uncertainty_score":0.005396962,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01611446395325749,"score_gpt":0.2229729308790228,"score_spread":0.2068584669257653,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}