{"id":"W1993376604","doi":"10.1016/s0045-6535(99)00278-7","title":"Experimental determination of the kinetic rate law for the oxidation of perchloroethylene by potassium permanganate","year":2000,"lang":"en","type":"article","venue":"Chemosphere","topic":"Advanced oxidation water treatment","field":"Environmental Science","cited_by":60,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Waterloo","funders":"Boeing","keywords":"Potassium permanganate; Tetrachloroethylene; Chemistry; Trichloroethylene; Aqueous solution; Permanganate; Reaction rate; Reaction rate constant; Solvent; Redox; Inorganic chemistry; Environmental chemistry; Nuclear chemistry; Kinetics; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00007785048,0.0000920965,0.00008261193,0.000001467995,0.000102628,0.000006888939,0.0001974501,0.00003151481,0.002314702],"category_scores_gemma":[0.000006653919,0.00005498674,0.00005606714,0.00007450711,0.0002193102,0.0001247045,0.00004087411,0.00003269659,0.00002342993],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009580945,"about_ca_system_score_gemma":0.000003463062,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000138104,"about_ca_topic_score_gemma":0.00002468941,"domain_scores_codex":[0.999395,0.00002852542,0.0001702206,0.0001503224,0.000147327,0.000108605],"domain_scores_gemma":[0.9995704,0.00005024192,0.000096986,0.0002523182,0.00001026958,0.00001977121],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002942129,0.00009008591,0.0002275437,0.000007587334,0.00000561767,6.802526e-8,0.0005319155,0.0006177571,0.9772187,0.00004107627,0.000315728,0.02091452],"study_design_scores_gemma":[0.0004023679,0.00004291346,0.003074015,0.000006558693,0.0000182374,0.00000103945,0.000158969,0.001114481,0.9896007,0.000165404,0.005355832,0.0000595504],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9957958,0.0001315887,0.0008194018,0.0003812134,0.00004082593,0.0004483931,0.00001735362,0.0000096904,0.002355729],"genre_scores_gemma":[0.9956879,0.00001113073,0.00159074,0.0001214712,0.000008977799,0.00006362403,0.00001791475,0.00001114738,0.00248711],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02085497,"threshold_uncertainty_score":0.9985973,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007216147618620477,"score_gpt":0.2301041853181803,"score_spread":0.2228880376995598,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}