{"id":"W1993419901","doi":"10.1107/s1600536806022021","title":"Absolute configuration of the <i>p</i>-nitrobenzoate ester of the cycloadduct of (<i>S</i>)-4-hydroxy-2-pentynoate and acetic acid 8-acetoxy-1,4-dihydro-1,4-methanonapththalen-5-yl ester","year":2006,"lang":"en","type":"article","venue":"Acta Crystallographica Section E Structure Reports Online","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph; University of Toronto","funders":"","keywords":"Absolute configuration; Chemistry; Hydrogen bond; Intermolecular force; Acetic acid; Molecule; Carboxylate; Stereochemistry; Crystal (programming language); Crystal structure; Absolute (philosophy); Medicinal chemistry; Crystallography; Organic chemistry; Philosophy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0003115757,0.0004315689,0.0007371787,0.0002677618,0.0001754749,0.00003133467,0.0003850243,0.0003898421,0.0001648771],"category_scores_gemma":[0.0001771043,0.0002765877,0.0005733686,0.001255823,0.0007642944,0.0002063697,0.0002017421,0.0004425928,8.59385e-9],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003606343,"about_ca_system_score_gemma":0.00009703532,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003734686,"about_ca_topic_score_gemma":0.0003885472,"domain_scores_codex":[0.9966429,0.0001136225,0.001492264,0.0006012524,0.0008159222,0.0003340073],"domain_scores_gemma":[0.9955583,0.0001190858,0.002577563,0.001321566,0.0003508544,0.00007269837],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004583145,0.0001518549,0.02065111,0.0002432558,0.0002560549,0.000005732453,0.0000856257,0.0001456488,0.9774726,0.000009016647,0.00009216445,0.0008411047],"study_design_scores_gemma":[0.00100326,0.0000925906,0.1690727,0.0003422881,0.001252369,0.001020014,0.0003143105,0.0001547287,0.8012026,0.002024391,0.02289528,0.0006254863],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9966711,0.0004819625,0.00009537561,0.0003376119,0.0003696717,0.0003528725,0.0003256074,0.00003827852,0.001327518],"genre_scores_gemma":[0.9989826,0.00008614095,0.00019371,0.00003416903,0.0001572797,0.00001482543,0.0001729065,0.00005164354,0.0003067457],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.17627,"threshold_uncertainty_score":0.9999686,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004334472091933969,"score_gpt":0.1952415533345013,"score_spread":0.1909070812425673,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}