{"id":"W1993449788","doi":"10.1021/ja037550s","title":"Scope of Palladium-Catalyzed Alkylative Ring Opening","year":2004,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":149,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Catalysis; Palladium; Nucleophile; Alkene; Ring (chemistry); Yield (engineering); Diethylzinc; Scope (computer science); Organic chemistry; Alkyl; Combinatorial chemistry; Enantioselective synthesis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00041542,0.0001413209,0.0004252516,0.00001578447,0.00007136622,0.00001965221,0.0005176559,0.00005496823,0.0002189714],"category_scores_gemma":[0.0005992756,0.0001019422,0.0006352841,0.0004300355,0.000476378,0.0001093291,0.0002034348,0.0004241471,0.000002372069],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003804,"about_ca_system_score_gemma":0.0002386085,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006038728,"about_ca_topic_score_gemma":4.973353e-7,"domain_scores_codex":[0.9985508,0.00002397606,0.0005811675,0.000144857,0.0005142618,0.0001849895],"domain_scores_gemma":[0.9977405,0.0002676805,0.001368697,0.0002714693,0.0002476755,0.0001039995],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006334998,0.00006179202,0.001001005,0.00003313395,0.0002047645,0.000001097641,0.0005121327,0.0009691796,0.995426,0.00005889321,0.0005197798,0.001148894],"study_design_scores_gemma":[0.0009475668,0.00001313815,0.0005621122,0.0001605982,0.00009495135,0.00007212683,0.0006573378,0.0000762644,0.995781,0.0005931228,0.0009202175,0.0001215779],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9917772,0.0001941681,0.005412226,0.0007851364,0.00009800174,0.00003459628,0.000009117408,0.00001222444,0.001677288],"genre_scores_gemma":[0.9651354,0.00008035522,0.03398406,0.0002932443,0.0003362398,0.000001597295,0.000003641642,0.00002557558,0.0001399036],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02857183,"threshold_uncertainty_score":0.4157083,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02034761669631328,"score_gpt":0.2981874095034541,"score_spread":0.2778397928071408,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}