{"id":"W1993461505","doi":"10.1021/ma010996d","title":"Atom Transfer Radical Polymerization of Methyl Methacrylate Mediated by Copper Bromide−Tetraethyldiethylenetriamine Grafted on Soluble and Recoverable Poly(ethylene-<i>b</i>-ethylene glycol) Supports","year":2001,"lang":"en","type":"article","venue":"Macromolecules","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":68,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Polymer chemistry; Atom-transfer radical-polymerization; Ethylene glycol; Methyl methacrylate; Chemistry; Polymerization; Catalysis; Polyethylene; Polyethylene glycol; Bromide; Ethylene; Chain transfer; Radical polymerization; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002664027,0.0004646103,0.00024651,0.000211469,0.0001162324,0.0002242685,0.0003807035,0.0003092719,0.001035795],"category_scores_gemma":[0.0002667756,0.0002577812,0.0002520024,0.0001444443,0.0001673287,0.0003395775,0.0001972102,0.0004846527,0.0004479269],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003100058,"about_ca_system_score_gemma":0.0002074469,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004581932,"about_ca_topic_score_gemma":0.0006284218,"domain_scores_codex":[0.9998804,0.00001891848,0.000009029034,0.0000266385,0.00002962323,0.00003523301],"domain_scores_gemma":[0.9998507,0.00002989131,0.0000504499,0.00002395448,0.0000188044,0.00002613642],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003273497,0.00001116818,0.00002376768,0.000021595,0.000002528384,0.00002684756,0.000007991292,0.00005596046,0.9988304,0.00007723758,0.00001415173,0.0008956142],"study_design_scores_gemma":[0.000009643633,0.00007789061,0.0002064141,0.000001938539,0.000003867825,0.00003527727,0.000002151909,0.000645633,0.9986181,0.00001170897,0.0003852289,0.000002179795],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9914792,0.0008525393,0.005527366,0.00005193153,0.00003111341,0.00003390635,0.00005790199,0.000122403,0.001843719],"genre_scores_gemma":[0.9887732,0.0005649149,0.005674798,0.00002135408,0.00001060393,0.00002290736,0.0001077318,0.00003311646,0.004791473],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001035795,"threshold_uncertainty_score":0.003465116,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007659883920406701,"score_gpt":0.2224643329499836,"score_spread":0.2148044490295769,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}