{"id":"W1993461505","doi":"10.1021/ma010996d","title":"Atom Transfer Radical Polymerization of Methyl Methacrylate Mediated by Copper Bromide−Tetraethyldiethylenetriamine Grafted on Soluble and Recoverable Poly(ethylene-<i>b</i>-ethylene glycol) Supports","year":2001,"lang":"en","type":"article","venue":"Macromolecules","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":68,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Polymer chemistry; Atom-transfer radical-polymerization; Ethylene glycol; Methyl methacrylate; Chemistry; Polymerization; Catalysis; Polyethylene; Polyethylene glycol; Bromide; Ethylene; Chain transfer; Radical polymerization; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003032573,0.0006268285,0.0008551555,0.0002241613,0.0002085611,0.00007375773,0.000318652,0.0005044253,0.001356404],"category_scores_gemma":[0.000151315,0.0006237149,0.0002073279,0.0005676138,0.0002797892,0.0002951275,0.0000733905,0.0003817903,0.00001774577],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007952368,"about_ca_system_score_gemma":0.00008298751,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002528867,"about_ca_topic_score_gemma":0.00002582016,"domain_scores_codex":[0.9965043,0.0001886555,0.001009746,0.0008947163,0.0006496116,0.00075296],"domain_scores_gemma":[0.9981757,0.000470338,0.0002944996,0.0005901422,0.0001124694,0.0003568537],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007646687,0.0003687422,0.001380315,0.0001105289,0.0001849952,0.00004682034,0.0002356689,0.000007926776,0.9727705,0.0001203211,0.0002596018,0.02374995],"study_design_scores_gemma":[0.002185076,0.0002144302,0.0003639915,0.0001684816,0.0001359084,0.00004047087,0.00009751065,0.0002123103,0.9808511,0.0001236803,0.01496305,0.0006439868],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9841534,0.00705401,0.00526282,0.0007441603,0.000253012,0.0002547026,0.0004870152,0.0002006224,0.00159027],"genre_scores_gemma":[0.9914727,0.004680169,0.0006003529,0.0004542561,0.0001214272,0.00006213684,0.001050296,0.000159852,0.001398773],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02310596,"threshold_uncertainty_score":0.9996214,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007659883920406701,"score_gpt":0.2224643329499836,"score_spread":0.2148044490295769,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}