{"id":"W1993610806","doi":"10.1021/ed300819r","title":"Green Carbonyl Condensation Reactions Demonstrating Solvent and Organocatalyst Recyclability","year":2013,"lang":"en","type":"article","venue":"Journal of Chemical Education","topic":"Chemistry and Chemical Engineering","field":"Environmental Science","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Faculty of Arts and Sciences; University of Pittsburgh","keywords":"Chemistry; Knoevenagel condensation; Green chemistry; Organic chemistry; Catalysis; Reactivity (psychology); Solvent; Condensation reaction; Polyethylene glycol; Organocatalysis; Reaction mechanism; Enantioselective synthesis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002332295,0.0005964143,0.0002339899,0.0003010285,0.0003149786,0.0002560819,0.000391314,0.0003749034,0.005254767],"category_scores_gemma":[0.0002529361,0.0002223852,0.0002930312,0.0003374815,0.0003276365,0.0004976229,0.0005671761,0.0007913528,0.001539008],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000310062,"about_ca_system_score_gemma":0.0002916891,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004939556,"about_ca_topic_score_gemma":0.001360289,"domain_scores_codex":[0.999721,0.00002834328,0.00001041103,0.00004679733,0.0001324516,0.00006103296],"domain_scores_gemma":[0.9998659,0.00002351899,0.00003368484,0.00002495127,0.00002714152,0.00002466326],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006395212,0.00003874348,0.0000543572,0.00009038472,0.000006441188,0.0002240983,0.00005128695,0.0002823611,0.9863906,0.0025884,0.0005005521,0.009708803],"study_design_scores_gemma":[0.000009276346,0.0002291751,0.000170897,0.00000570785,0.000005467582,0.0002354646,0.000009940399,0.0004087258,0.9908869,0.0003121315,0.007717222,0.000009055015],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6916761,0.005672695,0.1835344,0.00065456,0.0005205773,0.0003460336,0.00116932,0.003019617,0.1134066],"genre_scores_gemma":[0.9256518,0.003508717,0.04656387,0.0001709048,0.00008882603,0.00009708576,0.0005013113,0.0002870533,0.02313035],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005254767,"threshold_uncertainty_score":0.01757896,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004603343522577398,"score_gpt":0.2083376025746539,"score_spread":0.2037342590520765,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}