{"id":"W1993698251","doi":"10.1016/j.electacta.2011.01.067","title":"Mechanism and equivalent circuits in electrochemical impedance spectroscopy","year":2011,"lang":"en","type":"article","venue":"Electrochimica Acta","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":291,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada; University of Victoria","keywords":"Tafel equation; Dielectric spectroscopy; Equivalent circuit; Polarization (electrochemistry); Electrical impedance; Electronic circuit; Chemistry; Electrochemistry; Chemical physics; Electrode; Voltage; Physics; Physical chemistry; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008235274,0.0008549201,0.0007823928,0.0008686645,0.0005227579,0.001744226,0.003097979,0.002405002,0.007101084],"category_scores_gemma":[0.003266805,0.0004716941,0.0006848198,0.000619051,0.00157555,0.004970912,0.0009498214,0.00160741,0.001267621],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005235798,"about_ca_system_score_gemma":0.0002115432,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001317538,"about_ca_topic_score_gemma":0.00008716231,"domain_scores_codex":[0.9992884,0.000206758,0.0000619258,0.0001480872,0.0002411289,0.00005361301],"domain_scores_gemma":[0.9994059,0.0003244492,0.00004602352,0.000121732,0.00008166546,0.00002035057],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"theoretical_or_conceptual","study_design_gemma":"theoretical_or_conceptual","study_design_scores_codex":[0.0001007935,0.00009636499,0.000190753,0.0003203634,0.00001809978,0.00049495,0.0001781269,0.006609371,0.03979916,0.916459,0.002394434,0.03333861],"study_design_scores_gemma":[0.00005314805,0.0001158781,0.0004676282,0.00006820785,0.00005503969,0.001532783,0.00009938893,0.1647155,0.05308392,0.7619384,0.01780052,0.00006959354],"study_design_candidate":"theoretical_or_conceptual","study_design_consensus":"theoretical_or_conceptual","genre_codex":"methods","genre_gemma":"methods","genre_scores_codex":[0.0302306,0.004184063,0.9331785,0.002875246,0.0012112,0.0002259736,0.0003034602,0.0008041398,0.02698681],"genre_scores_gemma":[0.8222725,0.005274687,0.1360921,0.001484361,0.0009140107,0.0004884781,0.0003555479,0.0002505804,0.03286778],"genre_candidate":"methods","genre_consensus":"methods","teacher_disagreement_score":0.007101084,"threshold_uncertainty_score":0.02375549,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01552028236282465,"score_gpt":0.2315488750955249,"score_spread":0.2160285927327002,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}