{"id":"W1993787604","doi":"10.1039/b704899h","title":"Metal complexes of thiazyl radicals","year":2007,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organic and Molecular Conductors Research","field":"Materials Science","cited_by":113,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"","keywords":"Radical; Chemistry; Molecule; Intermolecular force; Ligand (biochemistry); Metal; Nitroxide mediated radical polymerization; Sulfur; Flexibility (engineering); Combinatorial chemistry; Nanotechnology; Materials science; Organic chemistry; Polymer; Mathematics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005160349,0.00006961126,0.0001402891,0.00008780408,0.0001090091,0.0000137798,0.0001626675,0.00005051214,0.004538366],"category_scores_gemma":[0.00001919963,0.00006129721,0.00007687166,0.0001723236,0.0001791447,0.00009164286,0.000005664203,0.0001033679,0.0001244394],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001893697,"about_ca_system_score_gemma":0.00006349432,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001541596,"about_ca_topic_score_gemma":0.0000675936,"domain_scores_codex":[0.9990535,0.00004520834,0.0002277058,0.0001513228,0.0002861271,0.0002361123],"domain_scores_gemma":[0.9995338,0.0000772641,0.00003646007,0.0001970109,0.00005075552,0.0001047175],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001385069,0.00007232664,0.00001351664,0.00001355702,0.00001050885,0.000004224001,0.0001570393,0.000006231357,0.9971962,0.001039357,0.00006536984,0.001407843],"study_design_scores_gemma":[0.0001823648,0.00004806234,0.0005173068,0.00000477076,0.00001798592,0.00001178222,0.0001493668,0.00001342734,0.9911143,0.0001269068,0.007749265,0.00006451755],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6659148,0.0001513669,0.3307416,0.0001788642,0.0002537491,0.0001192273,0.00005357147,0.00005207204,0.002534693],"genre_scores_gemma":[0.997337,0.0000163829,0.001960843,0.00003871842,0.00002873529,0.000002545892,0.000004516912,0.00001019986,0.0006010662],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3314222,"threshold_uncertainty_score":0.9963716,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03133184495919717,"score_gpt":0.3078422149136354,"score_spread":0.2765103699544383,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}