{"id":"W1993863537","doi":"10.1063/1.4739275","title":"Time-dependent partitioning theory of the control of radiationless transitions in 24-mode pyrazine","year":2012,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; University of British Columbia","funders":"U.S. Department of Defense; Defense Threat Reduction Agency; National Science Foundation","keywords":"Excited state; Pyrazine; Femtosecond; Excitation; Coherent control; Atomic physics; Population; Internal conversion; Ground state; Computation; Laser; Physics; Materials science; Chemistry; Optics; Quantum mechanics; Mathematics; Spectral line; Algorithm","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004169684,0.0004353319,0.0004351719,0.0003483935,0.0004316708,0.000709498,0.0008566962,0.000544352,0.002484994],"category_scores_gemma":[0.0007454463,0.0002503626,0.0003777054,0.0001702481,0.001128377,0.0006415968,0.0005677233,0.0004212023,0.0001542752],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001241441,"about_ca_system_score_gemma":0.0005912061,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003019976,"about_ca_topic_score_gemma":0.001626894,"domain_scores_codex":[0.9998943,0.00003332454,0.000002368974,0.00001256583,0.00002875158,0.00002875655],"domain_scores_gemma":[0.9997533,0.0001278238,0.00003820601,0.00001476806,0.00003583835,0.00002994615],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"theoretical_or_conceptual","study_design_scores_codex":[0.0001526243,0.00008057308,0.00044607,0.00009860108,0.00003410774,0.0001618016,0.0002502402,0.6515755,0.03548601,0.3049411,0.0003480971,0.006425249],"study_design_scores_gemma":[0.00001363249,0.00002990401,0.0001296595,0.000002608148,0.000002777647,0.000009474783,0.00001642516,0.9850737,0.001204,0.01326783,0.0002426809,0.0000074188],"study_design_candidate":"theoretical_or_conceptual","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7112502,0.0008339212,0.2641609,0.000510036,0.00006660911,0.0001094869,0.0000645227,0.0001196147,0.02288466],"genre_scores_gemma":[0.989222,0.0002091339,0.006416298,0.00003140562,0.000009285858,0.0000695609,0.0000164218,0.00003573555,0.003990086],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003019976,"threshold_uncertainty_score":0.009007335,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009754369883652692,"score_gpt":0.2460373253951657,"score_spread":0.236282955511513,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}