{"id":"W1993888054","doi":"10.1063/1.3291439","title":"Determination of outer-sphere dipolar time correlation functions from high-field NMR measurements. Example of a Gd3+ complex in a viscous solvent","year":2010,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Advanced MRI Techniques and Applications","field":"Medicine","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Indigenous and Northern Affairs Canada","keywords":"Diamagnetism; Chemistry; Spins; Relaxation (psychology); Spin (aerodynamics); Paramagnetism; Nuclear magnetic resonance; Analytical Chemistry (journal); Field (mathematics); Dipole; Molecular physics; Magnetic field; Condensed matter physics; Physics; Thermodynamics; Chromatography","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001960439,0.0004228163,0.0003111683,0.0002636568,0.0001891456,0.0002586044,0.0002759234,0.0003453638,0.0006749649],"category_scores_gemma":[0.0005740254,0.000125097,0.0001351173,0.0002623894,0.0003094973,0.0002681843,0.0001988069,0.0003993101,0.000181892],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002562961,"about_ca_system_score_gemma":0.0001663608,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001386543,"about_ca_topic_score_gemma":0.001080269,"domain_scores_codex":[0.9999168,0.00001761369,0.000003516408,0.00002434752,0.00002591125,0.00001183595],"domain_scores_gemma":[0.9997463,0.000111621,0.00006180368,0.00002082739,0.00002682067,0.0000326234],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008024027,0.000008830703,0.000195898,0.00005986043,0.000006969358,0.0001327144,0.00004414156,0.001269076,0.9958258,0.0004403605,0.000049764,0.001886433],"study_design_scores_gemma":[0.00001563865,0.0001666865,0.002579378,0.000006621873,0.00002223201,0.000317824,0.00005834319,0.03544672,0.9595401,0.0003799519,0.001445177,0.00002126338],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9454736,0.0009202218,0.0512522,0.00009510966,0.00001529495,0.0000306539,0.0001851069,0.0002251144,0.001802696],"genre_scores_gemma":[0.9751343,0.0006067592,0.02335289,0.00002982477,0.000007657335,0.0000204307,0.0001632293,0.00004785798,0.0006369992],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001386543,"threshold_uncertainty_score":0.002756894,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03627824775552223,"score_gpt":0.2943173598334281,"score_spread":0.2580391120779059,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}