{"id":"W1993958112","doi":"10.1039/c3dt00046j","title":"Lewis base complexes of AlH3: structural determination of monomeric and polymeric adducts by X-ray crystallography and DFT calculations","year":2013,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick","funders":"","keywords":"Adduct; Monomer; Lewis acids and bases; Crystallography; Chemistry; Base (topology); X-ray crystallography; Diffraction; Polymer; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00018487,0.0005818024,0.0006532186,0.0002215902,0.0004776164,0.0004909643,0.0009426847,0.0006676411,0.004429755],"category_scores_gemma":[0.0003054788,0.0003407714,0.0002959754,0.0003572871,0.0003876854,0.0004314281,0.0003626379,0.0008922836,0.0005729265],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0009599682,"about_ca_system_score_gemma":0.0003928186,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.004397932,"about_ca_topic_score_gemma":0.004299941,"domain_scores_codex":[0.9998932,0.00001304447,0.000004302383,0.00001821628,0.00004457832,0.00002664878],"domain_scores_gemma":[0.9999192,0.00002732456,0.00001112142,0.000009572532,0.00002055413,0.00001235528],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001517538,0.000564624,0.01009911,0.002867522,0.000342903,0.001366827,0.00105455,0.3926835,0.504604,0.03032782,0.0120003,0.04257128],"study_design_scores_gemma":[0.0004352478,0.001088086,0.007804128,0.00009603184,0.0001323611,0.0002758531,0.001164447,0.7712756,0.1963318,0.006448401,0.01484327,0.0001048443],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9848714,0.000832908,0.00418793,0.0002437175,0.00003591531,0.00003838142,0.001147767,0.0002132516,0.008428656],"genre_scores_gemma":[0.9950539,0.0005592028,0.002590043,0.00005664554,0.000009917355,0.00006546016,0.0008887716,0.0000520673,0.0007239142],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004429755,"threshold_uncertainty_score":0.01481903,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006771711740642977,"score_gpt":0.2265756300474596,"score_spread":0.2198039183068167,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}