{"id":"W1994031080","doi":"10.1021/jp046343r","title":"Hydrogen Atom Loss in Pyrimidine DNA Bases Induced by Low-Energy Electrons:  Energetics Predicted by Theory","year":2004,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"DNA and Nucleic Acid Chemistry","field":"Biochemistry, Genetics and Molecular Biology","cited_by":45,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Thymine; Chemistry; Uracil; Cytosine; Nucleobase; Pyrimidine; Base pair; Guanine; Hydrogen atom; Bond energy; Hydrogen bond; DNA; Photochemistry; Crystallography; Stereochemistry; Molecule; Nucleotide","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006436353,0.0007875549,0.0009953167,0.001043587,0.001262757,0.001047888,0.001569013,0.001399563,0.003731933],"category_scores_gemma":[0.001016552,0.0004390242,0.000873627,0.0006684217,0.001758021,0.001081128,0.001128929,0.001018249,0.0005684965],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001369459,"about_ca_system_score_gemma":0.0007294905,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003932423,"about_ca_topic_score_gemma":0.002306588,"domain_scores_codex":[0.999726,0.00004485947,0.000006326245,0.00001718724,0.0001021556,0.0001034818],"domain_scores_gemma":[0.999626,0.0001714601,0.00003848737,0.00005400482,0.0000577092,0.00005230863],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"theoretical_or_conceptual","study_design_scores_codex":[0.0001609617,0.0001276671,0.002372201,0.0003814645,0.00003936176,0.0007456191,0.0001802007,0.8552326,0.007136704,0.1255538,0.001506626,0.006562766],"study_design_scores_gemma":[0.00002852662,0.00003350072,0.0009233766,0.00002233622,0.000007789787,0.00006158178,0.00004831323,0.9597759,0.0007306419,0.03800231,0.0003468257,0.00001900201],"study_design_candidate":"theoretical_or_conceptual","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.842551,0.004553316,0.07488159,0.001137736,0.0003093222,0.000150188,0.0004261657,0.0003707973,0.07561986],"genre_scores_gemma":[0.9915568,0.001171356,0.003195582,0.0001591275,0.00004680191,0.0001437803,0.000219281,0.00006223712,0.003445056],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003932423,"threshold_uncertainty_score":0.01248455,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003009837834351345,"score_gpt":0.2048774787476432,"score_spread":0.2018676409132918,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}