{"id":"W1994084242","doi":"10.1021/ja107541w","title":"Umpolung Direct Arylation Reactions: Facile Process Requiring Only Catalytic Palladium and Substoichiometric Amount of Silver Salts","year":2010,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":52,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Umpolung; Palladium; Catalysis; Process (computing); Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005527088,0.0001592877,0.0003844255,0.00006966099,0.0001017322,0.00003115822,0.0002968379,0.00009396141,0.0001026159],"category_scores_gemma":[0.001486433,0.0001214684,0.0003360559,0.001001616,0.0004798971,0.0001842798,0.00008799085,0.0006380429,0.000001072384],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000195375,"about_ca_system_score_gemma":0.0002089983,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001010583,"about_ca_topic_score_gemma":0.00000417313,"domain_scores_codex":[0.9983829,0.00002221026,0.0006305968,0.0001968292,0.0005759515,0.0001914654],"domain_scores_gemma":[0.997277,0.0005721675,0.001404657,0.000294058,0.0003265779,0.0001255429],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004726224,0.00007947841,0.02503637,0.0001349361,0.000123234,4.96565e-7,0.0002912747,0.00008302518,0.9714475,0.00001281163,0.0005724995,0.002171121],"study_design_scores_gemma":[0.0007255081,0.00003063307,0.01953545,0.0001330464,0.0002442081,0.000289543,0.0007510998,0.001393296,0.9733192,0.0002774653,0.003029833,0.0002707279],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9982753,0.0001470443,0.0003054555,0.0003252777,0.0001856423,0.0000497945,0.00001772182,0.00001935392,0.000674443],"genre_scores_gemma":[0.9966599,0.00009162408,0.002531409,0.00009314727,0.0003243379,0.00000253167,0.000008033328,0.00002298403,0.0002659736],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005500914,"threshold_uncertainty_score":0.4953337,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01417303982326551,"score_gpt":0.287794613119035,"score_spread":0.2736215732957695,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}