{"id":"W1994264525","doi":"10.1016/j.synthmet.2013.05.014","title":"Kinetics and mechanism of pyrrole chemical polymerization","year":2013,"lang":"en","type":"article","venue":"Synthetic Metals","topic":"Conducting polymers and applications","field":"Materials Science","cited_by":209,"is_retracted":false,"has_abstract":false,"ca_institutions":"Mount Allison University","funders":"Natural Sciences and Engineering Research Council of Canada; Mount Allison University","keywords":"Polymerization; Chemistry; Kinetics; Pyrrole; Polymer chemistry; Chain-growth polymerization; Solution polymerization; Ionic polymerization; Polypyrrole; Chain transfer; Monomer; Enthalpy; Precipitation polymerization; Activation energy; Chemical kinetics; Photochemistry; Radical polymerization; Polymer; Organic chemistry; Thermodynamics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004668091,0.0003022375,0.000225709,0.0003311201,0.0002175633,0.0005134837,0.000452439,0.0003577503,0.005237654],"category_scores_gemma":[0.0009255322,0.0003353535,0.0002415066,0.0001724457,0.0003931891,0.00101541,0.0001679151,0.0007594729,0.0008739301],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0009017332,"about_ca_system_score_gemma":0.0003307242,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001128931,"about_ca_topic_score_gemma":0.0006065628,"domain_scores_codex":[0.9997962,0.00002491536,0.000008897947,0.00005534984,0.00005715532,0.00005735287],"domain_scores_gemma":[0.9996036,0.0002404097,0.00005774952,0.00003000578,0.00004113906,0.00002713655],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005974668,0.0001471926,0.0007703892,0.0002542939,0.00001970014,0.0002063475,0.0002135572,0.004167023,0.9675457,0.01072184,0.0006120371,0.01474442],"study_design_scores_gemma":[0.00001910561,0.000108027,0.00151656,0.000008348024,0.000008433517,0.0001170969,0.00002746122,0.0149589,0.9795512,0.0008021424,0.002863035,0.00001966169],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9642403,0.003615154,0.01660813,0.0004868291,0.00008653446,0.00008620852,0.0006585402,0.0003884084,0.01382986],"genre_scores_gemma":[0.9927307,0.0007305823,0.001257908,0.00003273615,0.00001234874,0.000022754,0.0001726625,0.00002306122,0.005017368],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005237654,"threshold_uncertainty_score":0.01752174,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01407145649128099,"score_gpt":0.2325970090485949,"score_spread":0.2185255525573139,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}