{"id":"W1994283688","doi":"10.1021/la000234w","title":"Sequential Selective Formation of Adsorbed<i>tert</i>-Butoxy and<i>tert</i>-Butyl Groups from<i>tert</i>-Butyl Formate on Ni(111)","year":2000,"lang":"he","type":"article","venue":"Langmuir","topic":"Catalysis and Oxidation Reactions","field":"Chemical Engineering","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Chemistry; Formate; Adsorption; Carbon monoxide; Thermal desorption; X-ray photoelectron spectroscopy; Decomposition; Desorption; Infrared spectroscopy; Reactivity (psychology); Thermal decomposition; Inorganic chemistry; Medicinal chemistry; Hydrogen; Thermal desorption spectroscopy; Photochemistry; Physical chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001403482,0.0003677816,0.0003062583,0.0001354079,0.0001449641,0.000313617,0.0002917442,0.0002382408,0.001069487],"category_scores_gemma":[0.0002931084,0.0002865572,0.0002118181,0.0001206754,0.0002023151,0.0003696058,0.0002061277,0.0003749541,0.0002617647],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001783811,"about_ca_system_score_gemma":0.0001559595,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003354445,"about_ca_topic_score_gemma":0.0005752133,"domain_scores_codex":[0.9998748,0.00001078611,0.000006241188,0.00003157264,0.00003541054,0.00004120076],"domain_scores_gemma":[0.9998678,0.00003766911,0.00003127779,0.0000199656,0.0000219523,0.00002133341],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006276753,0.000005116635,0.0001270659,0.00004004018,0.000002736487,0.00004196511,0.00002616413,0.00006323092,0.9988376,0.0000584519,0.00001668497,0.0007181215],"study_design_scores_gemma":[0.000003262465,0.0000305564,0.0004697723,0.000001045231,0.000002573792,0.0000274733,0.000008998004,0.0002788427,0.9989635,0.00001416385,0.0001980932,0.000001763294],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9952852,0.0004435397,0.003011931,0.00003656156,0.00001670066,0.00002902854,0.0001478922,0.00004750755,0.000981518],"genre_scores_gemma":[0.9953163,0.0003874194,0.002485737,0.00002252633,0.000005445324,0.00003251079,0.0002163942,0.00002364929,0.001510044],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001069487,"threshold_uncertainty_score":0.003577769,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00890994634243812,"score_gpt":0.2207789391319451,"score_spread":0.211868992789507,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}