{"id":"W1994283688","doi":"10.1021/la000234w","title":"Sequential Selective Formation of Adsorbed<i>tert</i>-Butoxy and<i>tert</i>-Butyl Groups from<i>tert</i>-Butyl Formate on Ni(111)","year":2000,"lang":"he","type":"article","venue":"Langmuir","topic":"Catalysis and Oxidation Reactions","field":"Chemical Engineering","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Chemistry; Formate; Adsorption; Carbon monoxide; Thermal desorption; X-ray photoelectron spectroscopy; Decomposition; Desorption; Infrared spectroscopy; Reactivity (psychology); Thermal decomposition; Inorganic chemistry; Medicinal chemistry; Hydrogen; Thermal desorption spectroscopy; Photochemistry; Physical chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0002654477,0.0007527446,0.0009884152,0.0003376477,0.0003274422,0.0002008923,0.0004334179,0.0005338067,0.002636323],"category_scores_gemma":[0.00005085503,0.000738482,0.0004539753,0.0006839251,0.0001423931,0.001118891,0.0001407463,0.0007627461,0.0009524863],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002970388,"about_ca_system_score_gemma":0.00005172938,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001139873,"about_ca_topic_score_gemma":0.0001953395,"domain_scores_codex":[0.9961815,0.0001287271,0.001323364,0.000789687,0.0007159497,0.0008607476],"domain_scores_gemma":[0.9979963,0.0002489357,0.0004904981,0.0007472956,0.0001993128,0.0003176705],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.003012164,0.002242938,0.001534863,0.001716677,0.001973143,0.0001014494,0.02383738,0.00389737,0.8224471,0.0039826,0.03283987,0.1024145],"study_design_scores_gemma":[0.007710777,0.0008659664,0.007801809,0.001107821,0.001522816,0.0001716718,0.001166756,0.06400508,0.7601171,0.0009727419,0.1517873,0.002770188],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9807683,0.0007500587,0.00264644,0.0007377419,0.0005227849,0.0006699532,0.001458504,0.000359133,0.01208714],"genre_scores_gemma":[0.9930495,0.0007349795,0.0003111805,0.0006509459,0.0006795675,0.0000837859,0.001826587,0.0001179046,0.002545554],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1189474,"threshold_uncertainty_score":0.9998254,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00890994634243812,"score_gpt":0.2207789391319451,"score_spread":0.211868992789507,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}