{"id":"W1994344287","doi":"10.1007/s11244-010-9532-6","title":"SiliaCat ® S-Pd and SiliaCat DPP-Pd: Highly Reactive and Reusable Heterogeneous Silica-Based Palladium Catalysts","year":2010,"lang":"en","type":"article","venue":"Topics in Catalysis","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":64,"is_retracted":false,"has_abstract":false,"ca_institutions":"SiliCycle (Canada)","funders":"","keywords":"Palladium; Sonogashira coupling; Catalysis; Heterogeneous catalysis; Chemistry; Suzuki reaction; Combinatorial chemistry; Materials science; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003257866,0.0006295999,0.000277184,0.0005536513,0.0001212091,0.0003871676,0.0009375549,0.0004167715,0.001377552],"category_scores_gemma":[0.0002392809,0.000396336,0.0003487116,0.0003517166,0.0003493388,0.0006265622,0.0005926518,0.0005646467,0.001023646],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003737823,"about_ca_system_score_gemma":0.0002419637,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000541878,"about_ca_topic_score_gemma":0.001024368,"domain_scores_codex":[0.9997283,0.00003204997,0.00002462302,0.00005423445,0.00009596876,0.00006483479],"domain_scores_gemma":[0.9999294,0.00001104208,0.00001693303,0.000009843651,0.00001027844,0.0000224575],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002947859,0.00006193886,0.0002382411,0.0002589943,0.00005514822,0.0001881419,0.00007236333,0.0005944142,0.9872369,0.001502971,0.0004555394,0.009040531],"study_design_scores_gemma":[0.00001784539,0.0001673414,0.0004655579,0.000003717736,0.00002620394,0.000153153,0.00001356516,0.0007119785,0.9954119,0.0001063589,0.002914998,0.000007379709],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9409069,0.006869678,0.03145584,0.0001802908,0.0001321021,0.0001211316,0.0005356592,0.0009274971,0.01887085],"genre_scores_gemma":[0.9881052,0.00168917,0.004033814,0.00005696559,0.00003315272,0.00002519231,0.0003287046,0.00005374519,0.005674167],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001377552,"threshold_uncertainty_score":0.004608393,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00808416360121198,"score_gpt":0.2511271128287201,"score_spread":0.2430429492275081,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}