{"id":"W1994373916","doi":"10.1021/ol201125h","title":"Homologous Mukaiyama Reactions via Trapping of the Nazarov Intermediate with Silyloxyalkenes","year":2011,"lang":"en","type":"article","venue":"Organic Letters","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":41,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Stereocenter; Domino; Trapping; Combinatorial chemistry; Trap (plumbing); Organic chemistry; Catalysis; Enantioselective synthesis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008160078,0.0001396238,0.0001904768,0.00006265801,0.00008975065,0.000007829593,0.0003405331,0.00006578634,0.0009121975],"category_scores_gemma":[0.00005468083,0.00009005221,0.0001165256,0.0003758654,0.0001627643,0.00006474573,0.00006045024,0.0001531692,0.00002470384],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005096748,"about_ca_system_score_gemma":0.00002633668,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001569772,"about_ca_topic_score_gemma":0.00002998465,"domain_scores_codex":[0.9991678,0.00002038714,0.0002285623,0.0002113274,0.0001732732,0.0001986303],"domain_scores_gemma":[0.9991333,0.00007772491,0.0002042455,0.000513449,0.00002850718,0.00004279898],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002218188,0.00007667773,0.007410929,0.0000439917,0.0002148403,0.00001145029,0.0009448074,8.493865e-7,0.979752,0.00001712333,0.0003751252,0.01112999],"study_design_scores_gemma":[0.0002007324,0.0000145116,0.01016,0.00004721109,0.0001384403,0.00004664695,0.0004894464,0.00001044237,0.988331,0.00001290711,0.0004048871,0.000143796],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9930432,0.00005171718,0.001005222,0.0005490886,0.00008759851,0.00003889187,0.000005626616,0.00005006143,0.005168607],"genre_scores_gemma":[0.9992275,0.00001149942,0.0001445755,0.0003214594,0.00006939749,0.00001018578,0.000003023853,0.00002792092,0.0001844398],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0109862,"threshold_uncertainty_score":0.9987923,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009997935425379948,"score_gpt":0.1732768144996382,"score_spread":0.1632788790742582,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}