{"id":"W1994416178","doi":"10.1002/chem.201202475","title":"Quantum‐Chemical and Electrochemical Investigation of the Electrochemical Windows of Halogenated Carborate Anions","year":2012,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Boron Compounds in Chemistry","field":"Medicine","cited_by":46,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Lethbridge","funders":"Deutsche Forschungsgemeinschaft","keywords":"Electrochemistry; Chemistry; Redox; Halogen; Substituent; Electrolyte; Electron affinity (data page); Cyclic voltammetry; Ionization; Chemical stability; Ionization energy; Affinities; Physical chemistry; Inorganic chemistry; Computational chemistry; Ion; Molecule; Stereochemistry; Electrode; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003839394,0.0002479914,0.0002814826,0.0001507516,0.0001648759,0.0003165326,0.0006179455,0.0004434745,0.0009103474],"category_scores_gemma":[0.0005869279,0.000136282,0.000135905,0.0001921022,0.000350558,0.0002291005,0.0002226714,0.000402646,0.00009960476],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003301033,"about_ca_system_score_gemma":0.0001358871,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006757608,"about_ca_topic_score_gemma":0.0007795083,"domain_scores_codex":[0.9997461,0.0000379599,0.00001465922,0.00005621893,0.0001139163,0.00003105053],"domain_scores_gemma":[0.9998406,0.00005434747,0.00003064162,0.00001066366,0.00004873484,0.00001500447],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007979482,0.00001733503,0.0002908037,0.00007814257,0.00001067313,0.00004336156,0.00005109718,0.000407841,0.9958995,0.0004896862,0.00005250553,0.002579299],"study_design_scores_gemma":[0.00001831406,0.0001697622,0.001245494,0.000006295314,0.0000120461,0.00008377917,0.00003575195,0.004279942,0.992859,0.0001081306,0.001169641,0.00001189162],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.994494,0.001153355,0.003122024,0.00006832963,0.00001668299,0.00001070642,0.0001251882,0.00003735339,0.0009723569],"genre_scores_gemma":[0.9957288,0.0006169582,0.003017796,0.00002139666,0.000007968317,0.00001599741,0.0001056714,0.000006699209,0.0004786746],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009103474,"threshold_uncertainty_score":0.00304538,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.016957212199241,"score_gpt":0.2352805924603495,"score_spread":0.2183233802611085,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}