{"id":"W1994542513","doi":"10.1021/ja906429c","title":"Catalytic Asymmetric Synthesis of Palmerolide A via Organoboron Methodology","year":2009,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Marine Sponges and Natural Products","field":"Biochemistry, Genetics and Molecular Biology","cited_by":83,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Enantioselective synthesis; Chemistry; Catalysis; Context (archaeology); Diol; Combinatorial chemistry; Stoichiometry; Sequence (biology); Natural product; Claisen rearrangement; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001431613,0.0005107338,0.0002800176,0.0003288598,0.0002970548,0.000249242,0.0004131904,0.0003353797,0.003267361],"category_scores_gemma":[0.0001511637,0.0001729922,0.0002093562,0.0003163196,0.0002806436,0.0003567269,0.0004421784,0.0006659231,0.001641886],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003051804,"about_ca_system_score_gemma":0.0008641668,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005064271,"about_ca_topic_score_gemma":0.001004847,"domain_scores_codex":[0.9999079,0.00001567798,0.00000887968,0.00002113636,0.00001815166,0.00002838778],"domain_scores_gemma":[0.9999529,0.000007076995,0.000009173575,0.000009082744,0.000007116636,0.00001461235],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000196921,0.0001083768,0.0001640918,0.0004581556,0.00003215997,0.001080832,0.0001034861,0.001209548,0.9630302,0.006511749,0.001032799,0.02607183],"study_design_scores_gemma":[0.0001128326,0.0006318334,0.000469522,0.0000191212,0.00002583112,0.0009824465,0.00006423173,0.0008768847,0.9614779,0.001375589,0.03392419,0.00003981641],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8013093,0.006554118,0.1029787,0.0006933734,0.0008154652,0.0008211512,0.00231118,0.0008595751,0.08365712],"genre_scores_gemma":[0.9595137,0.004146731,0.02592048,0.0001431819,0.00005987099,0.0002039668,0.0006384086,0.00005833141,0.009315313],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003267361,"threshold_uncertainty_score":0.01093036,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01242194459495549,"score_gpt":0.2733491914701924,"score_spread":0.2609272468752369,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}