{"id":"W1994639365","doi":"10.1021/om800157s","title":"Reactivity of Cp*Mo(NO)(═CHCMe<sub>3</sub>) with Olefins and Dienes: C−H Activation Reactions of Molybdenacyclobutanes","year":2008,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Diene; Cyclopentene; Cycloheptene; Allylic rearrangement; Cyclohexene; Cycloalkene; Reactivity (psychology); Medicinal chemistry; Cyclooctene; Metathesis; Ethylene; Stereochemistry; Olefin fiber; Norbornene; Hydride; Organic chemistry; Metal; Catalysis; Polymerization","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008689251,0.0003708174,0.00015041,0.000138471,0.0001506159,0.0002560208,0.0001685036,0.0002821059,0.001174626],"category_scores_gemma":[0.0001279574,0.0001280385,0.0001400863,0.0001027299,0.0001716408,0.000177219,0.000228656,0.0002553297,0.0001964739],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002769075,"about_ca_system_score_gemma":0.0001160317,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008437319,"about_ca_topic_score_gemma":0.001858451,"domain_scores_codex":[0.9999127,0.000009525698,0.000004052389,0.00001544567,0.00002096724,0.00003721127],"domain_scores_gemma":[0.9999541,0.000008547787,0.00001251845,0.000005273899,0.000005930248,0.00001355928],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001576219,0.00002579239,0.0005643899,0.00007702058,0.00001750832,0.0001172408,0.00005167501,0.000194354,0.996811,0.0002229457,0.0000503159,0.001710222],"study_design_scores_gemma":[0.000007211369,0.0001320689,0.001406972,0.000004293581,0.000007501748,0.000089713,0.00001744373,0.0002990858,0.9971161,0.00002234784,0.0008937148,0.000003587764],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9975921,0.0004076182,0.000350842,0.0000170209,0.000008319686,0.00001039663,0.00004083012,0.00001265046,0.001560158],"genre_scores_gemma":[0.9981384,0.0002857346,0.000377198,0.00001101896,0.000002360376,0.000006378621,0.00007992061,0.000007713673,0.001091195],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001174626,"threshold_uncertainty_score":0.003929496,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01610389567941383,"score_gpt":0.2210511134728275,"score_spread":0.2049472177934137,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}