{"id":"W1994639365","doi":"10.1021/om800157s","title":"Reactivity of Cp*Mo(NO)(═CHCMe<sub>3</sub>) with Olefins and Dienes: C−H Activation Reactions of Molybdenacyclobutanes","year":2008,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Diene; Cyclopentene; Cycloheptene; Allylic rearrangement; Cyclohexene; Cycloalkene; Reactivity (psychology); Medicinal chemistry; Cyclooctene; Metathesis; Ethylene; Stereochemistry; Olefin fiber; Norbornene; Hydride; Organic chemistry; Metal; Catalysis; Polymerization","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002104538,0.0002924186,0.0005265332,0.00008645884,0.0001107881,0.000009899936,0.0002014384,0.0002185148,0.0002475746],"category_scores_gemma":[0.000762161,0.0002727355,0.00008929367,0.0004556135,0.0004259976,0.0002043228,0.00009733332,0.0002513741,0.000006685399],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009532744,"about_ca_system_score_gemma":0.0001323652,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000581833,"about_ca_topic_score_gemma":0.000006809072,"domain_scores_codex":[0.9983805,0.00004149807,0.0004884588,0.0004363038,0.0003953717,0.0002578015],"domain_scores_gemma":[0.9980164,0.0004660309,0.00053653,0.0006192056,0.0002372649,0.0001245637],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008671482,0.0003228388,0.003243997,0.000342403,0.0001072723,0.000005580363,0.0003027821,0.000005562918,0.9928201,0.00007078907,0.00001289492,0.002679107],"study_design_scores_gemma":[0.0005015038,0.00004753735,0.00403979,0.000129527,0.00009456602,0.0002479349,0.0002604642,0.00003229367,0.9934323,0.0001142299,0.0008309022,0.0002688895],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9932242,0.00006208885,0.0006956357,0.00005432119,0.00003040879,0.00008409159,0.00004323613,0.00007819248,0.005727825],"genre_scores_gemma":[0.9956908,0.0004445032,0.003254024,0.000007934613,0.0000885707,0.00001095762,0.00002186924,0.00006531191,0.0004160923],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005311733,"threshold_uncertainty_score":0.9999725,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01610389567941383,"score_gpt":0.2210511134728275,"score_spread":0.2049472177934137,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}