{"id":"W1994721258","doi":"10.1039/b009494n","title":"Absolute rate constants for some reactions of the triethylamine-boryl radical and the borane radical anion","year":2001,"lang":"en","type":"article","venue":"Journal of the Chemical Society Perkin Transactions 2","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":56,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences","funders":"","keywords":"Chemistry; Reaction rate constant; Radical; Flash photolysis; Photochemistry; Nucleophile; Hydrogen atom abstraction; Medicinal chemistry; Peroxide; Homolysis; Triethylamine; Kinetics; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001326937,0.0009409774,0.0007445177,0.000503386,0.0003375787,0.0004206291,0.001305025,0.0008852007,0.005190136],"category_scores_gemma":[0.001640842,0.0004446263,0.0009129068,0.0003935746,0.0003718653,0.001034879,0.0003252553,0.001744186,0.001800409],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001225794,"about_ca_system_score_gemma":0.0006953063,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001281648,"about_ca_topic_score_gemma":0.0009959552,"domain_scores_codex":[0.9994641,0.00006375509,0.00003862312,0.0001835471,0.0001165186,0.0001334543],"domain_scores_gemma":[0.9985507,0.0008500985,0.0001889313,0.0001161376,0.0002239213,0.00007019666],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008554301,0.0001242763,0.002237659,0.0006108818,0.00009493848,0.00009181286,0.0002604016,0.002562103,0.9749393,0.001471897,0.0002687797,0.0164825],"study_design_scores_gemma":[0.00001971306,0.0003619718,0.001849436,0.00001380991,0.00004696866,0.000111041,0.00005017485,0.003444714,0.9922059,0.0001849859,0.00167771,0.00003356158],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9581649,0.005836317,0.0307516,0.0002273659,0.0001124933,0.0002363312,0.00155646,0.0004950774,0.002619467],"genre_scores_gemma":[0.9724661,0.0036812,0.01215289,0.00004245829,0.00002922229,0.0004586711,0.002842542,0.0001160385,0.008210971],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005190136,"threshold_uncertainty_score":0.01736271,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01024666536507441,"score_gpt":0.2460067273573858,"score_spread":0.2357600619923114,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}