{"id":"W1994782511","doi":"10.1246/bcsj.76.1397","title":"One-Pot Speciation Method for Cr(III) and Cr(VI) with APCD/DIBK Extraction System Based on Difference in Rate of Complex Formation","year":2003,"lang":"en","type":"article","venue":"Bulletin of the Chemical Society of Japan","topic":"Analytical chemistry methods development","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"Saint Paul University","funders":"","keywords":"Chemistry; Chromium; Extraction (chemistry); Certified reference materials; Detection limit; Genetic algorithm; Analytical Chemistry (journal); Seawater; Inorganic chemistry; Chromatography","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0007456146,0.0001642002,0.0004134167,0.00001283268,0.00004177547,0.000007707455,0.0001708408,0.0001756997,0.0001271098],"category_scores_gemma":[0.0003296531,0.0001325461,0.000165865,0.0001030378,0.0001360495,0.00001531744,0.00003245857,0.0001847231,3.892554e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002298533,"about_ca_system_score_gemma":0.000040832,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003236901,"about_ca_topic_score_gemma":7.687661e-7,"domain_scores_codex":[0.9986732,0.0000729675,0.0005560454,0.0002418479,0.0002775349,0.0001783996],"domain_scores_gemma":[0.9981466,0.0008613396,0.0005447377,0.0002547622,0.0001397691,0.00005277538],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002631523,0.0001883286,0.0005970754,0.002342559,0.00004801008,2.692541e-8,0.0002099483,0.0000939836,0.9949078,0.0002926101,0.0003389881,0.0007175072],"study_design_scores_gemma":[0.001428523,0.00002551875,0.001324621,0.0005126493,0.00005780498,0.000001820048,0.0006238652,0.0132058,0.9819162,0.0001949047,0.0005660952,0.0001421839],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8397545,0.00002538185,0.1513364,0.00164421,0.00002535899,0.0004926093,0.00004042714,0.00003381509,0.006647351],"genre_scores_gemma":[0.801425,0.000004537889,0.1982567,0.00006490653,0.00001846264,0.00002482283,0.00001805022,0.00001302134,0.0001744605],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0469203,"threshold_uncertainty_score":0.5405073,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03266081383723179,"score_gpt":0.2743546344744711,"score_spread":0.2416938206372393,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}