{"id":"W1994787003","doi":"10.1063/1.3526487","title":"π-conjugation and charge polarization in fluorene-dibenzothiophene-<i>S,S</i>-dioxide co-oligomers by Raman spectroscopy and quantum chemistry","year":2011,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Organic Electronics and Photovoltaics","field":"Engineering","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Ministerio de Ciencia y Tecnología","keywords":"Fluorene; Raman spectroscopy; Quantum chemistry; Dibenzothiophene; Photochemistry; Polarization (electrochemistry); Spectroscopy; Chemistry; Quantum; Chemical physics; Materials science; Physical chemistry; Physics; Organic chemistry; Polymer; Optics; Reaction mechanism; Quantum mechanics; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007075516,0.0001985048,0.00008690171,0.0001031826,0.000122359,0.0001444866,0.0000970531,0.0001534267,0.0006615014],"category_scores_gemma":[0.0001256195,0.0001128145,0.0001283313,0.0001525318,0.0002062018,0.000209191,0.00008181472,0.0001499579,0.00005725149],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002477534,"about_ca_system_score_gemma":0.0001288447,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007433862,"about_ca_topic_score_gemma":0.001372963,"domain_scores_codex":[0.9999633,0.000006883577,0.000001437603,0.000007413691,0.00001559494,0.000005378889],"domain_scores_gemma":[0.9999593,0.00001917722,0.00001058508,0.00000262993,0.000004614341,0.000003581814],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001104233,0.00006021588,0.002124246,0.00008335429,0.00001124001,0.0001002525,0.0001156018,0.02228251,0.9682704,0.002507435,0.00005662312,0.004277741],"study_design_scores_gemma":[0.00002174217,0.0003621476,0.006784937,0.00001087193,0.00002548077,0.00009997375,0.00007142063,0.1240396,0.867071,0.0005627765,0.0009278912,0.00002218088],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9984202,0.00007254522,0.0009577011,0.00001102279,0.000001511231,0.000002518196,0.00001433018,0.000007138765,0.0005129559],"genre_scores_gemma":[0.9988949,0.00007468266,0.0007917431,0.000002307856,6.28849e-7,0.000003335042,0.00002208409,0.000002429803,0.0002080508],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007433862,"threshold_uncertainty_score":0.002212942,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00616090234765162,"score_gpt":0.1920659096620184,"score_spread":0.1859050073143668,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}