{"id":"W1994932242","doi":"10.1002/ejic.200700826","title":"Preparation and Characterization of a Ligand‐Stabilized Trimethylphosphane Dication","year":2007,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":60,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick; Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Dication; Chemistry; Trifluoromethanesulfonate; Ligand (biochemistry); Salt (chemistry); Medicinal chemistry; Polymer chemistry; Organic chemistry; Catalysis; Molecule","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001947981,0.0002254148,0.0002033314,0.0001920273,0.0001885758,0.0001985042,0.000185969,0.0002615943,0.002213621],"category_scores_gemma":[0.0004511783,0.0001074178,0.00010047,0.0001717033,0.0001383808,0.0001347064,0.0001935942,0.0002862028,0.0007623727],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001869511,"about_ca_system_score_gemma":0.0001543151,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00039312,"about_ca_topic_score_gemma":0.0005031358,"domain_scores_codex":[0.9998724,0.00001594159,0.00001246824,0.00003582496,0.00004416515,0.00001906347],"domain_scores_gemma":[0.9998079,0.00002437242,0.00002791086,0.00003093163,0.0000575109,0.00005142212],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003527152,0.000004979091,0.00004599729,0.00002320709,0.000002549241,0.00003175383,0.00001280704,0.00005712894,0.9985849,0.00003556593,0.00005196215,0.001114042],"study_design_scores_gemma":[0.000006872693,0.00008675078,0.0002450625,0.00000133402,0.000003693593,0.00007518294,0.000004043648,0.0001585238,0.9978644,0.000006706532,0.001545234,0.000002151039],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9865216,0.0007762345,0.008701584,0.00007676826,0.00004120037,0.0001138743,0.000676106,0.0001787939,0.002913896],"genre_scores_gemma":[0.9818745,0.0004077502,0.01003628,0.00006881258,0.00001485601,0.0000804885,0.001535019,0.00008917043,0.005893108],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002213621,"threshold_uncertainty_score":0.007405341,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006814129389303617,"score_gpt":0.2210852999986802,"score_spread":0.2142711706093766,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}