{"id":"W1994932242","doi":"10.1002/ejic.200700826","title":"Preparation and Characterization of a Ligand‐Stabilized Trimethylphosphane Dication","year":2007,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":60,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick; Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Dication; Chemistry; Trifluoromethanesulfonate; Ligand (biochemistry); Salt (chemistry); Medicinal chemistry; Polymer chemistry; Organic chemistry; Catalysis; Molecule","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001168994,0.0001681494,0.0002974319,0.00004596688,0.00005020944,0.00003064295,0.0002571773,0.00006651874,0.0004910696],"category_scores_gemma":[0.0004226895,0.000165261,0.00008356654,0.0001907235,0.00008502827,0.0001602808,0.00006312784,0.0002267287,0.000006029681],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008681008,"about_ca_system_score_gemma":0.00009185461,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000001124587,"about_ca_topic_score_gemma":1.581775e-7,"domain_scores_codex":[0.9983361,0.00003866847,0.0009717948,0.0001818442,0.0003028689,0.0001687529],"domain_scores_gemma":[0.9979813,0.0001343633,0.001200179,0.0002801486,0.0002627673,0.0001412305],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003070521,0.0001070599,0.001551078,0.000155154,0.000050925,0.00002250252,0.000566221,2.477006e-7,0.9915435,0.000002231152,0.0000208131,0.005673221],"study_design_scores_gemma":[0.0009168941,0.00004810963,0.006267658,0.0001328179,0.00006564884,0.000186895,0.0001463201,0.000007814053,0.9908974,0.0000116469,0.00117882,0.0001399933],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9943078,0.0004252822,0.0007510966,0.00006721768,0.0000619535,0.00003586162,0.000006952219,0.00002558081,0.004318242],"genre_scores_gemma":[0.9985369,0.0001933238,0.0005870913,0.00001422578,0.0002581907,2.4069e-7,0.00001407055,0.00004314194,0.0003528486],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005533227,"threshold_uncertainty_score":0.6739149,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006814129389303617,"score_gpt":0.2210852999986802,"score_spread":0.2142711706093766,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}