{"id":"W1995103857","doi":"10.1002/ejic.200400310","title":"18‐Crown‐6 and Titanium Tetrafluoride − Preparation of the Ti<sup>IV</sup> Fluoride Crown Ether Complexes (TiF<sub>4</sub>)<sub>2</sub>(18‐Crown‐6) and the Stabilization of <i>cis‐</i>TiF<sub>4</sub>(H<sub>2</sub>O)<sub>2</sub> in [{<i>cis‐</i>TiF<sub>4</sub>(H<sub>2</sub>O)<sub>2</sub>}<sub>2</sub>(18‐Crown‐6)]","year":2004,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick; Dalhousie University","funders":"","keywords":"Chemistry; Crown ether; Fluoride; Titanium; Crown (dentistry); Inorganic chemistry; Medicinal chemistry; Nuclear magnetic resonance spectroscopy; 18-Crown-6; Crystallography; Molecule; Stereochemistry; Ion; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.01021394,0.00857679,0.008722655,0.002308959,0.004189879,0.002901906,0.008061096,0.004926022,0.0003063939],"category_scores_gemma":[0.004092832,0.008039642,0.004731222,0.007815434,0.006662325,0.004530394,0.004593051,0.01367333,0.0007814582],"about_ca_system_candidate":true,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.005271264,"about_ca_system_score_gemma":0.005237631,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001198002,"about_ca_topic_score_gemma":0.0005287862,"domain_scores_codex":[0.9572579,0.003991972,0.01481957,0.00788318,0.0082206,0.007826743],"domain_scores_gemma":[0.9668376,0.003461546,0.01224821,0.008302325,0.005210237,0.003940028],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.006515167,0.003411718,0.001356513,0.003764718,0.003684031,0.001538185,0.006218193,0.004786414,0.944706,0.0001971137,0.01185369,0.0119683],"study_design_scores_gemma":[0.02212877,0.001398664,0.00247836,0.005709286,0.003763364,0.006135259,0.003546235,0.001398582,0.9432027,0.001232732,0.001296477,0.007709515],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9761629,0.007863326,0.00126404,0.001400567,0.003532445,0.004257555,0.001588848,0.001374274,0.002556056],"genre_scores_gemma":[0.9713067,0.01689285,0.0003504271,0.00132971,0.005461446,0.0002982551,0.001317522,0.002949434,0.00009365938],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0156136,"threshold_uncertainty_score":0.9999965,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008955615505249549,"score_gpt":0.2089112856817891,"score_spread":0.1999556701765396,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}