{"id":"W1995117269","doi":"10.1021/ja803435w","title":"Beyond Aresta’s Complex: Ni- and Pd-Catalyzed Organozinc Coupling with CO<sub>2</sub>","year":2008,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":302,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Reagent; Negishi coupling; Organic synthesis; Catalysis; Combinatorial chemistry; Compatibility (geochemistry); Enantioselective synthesis; Electrophile; Functional group; Stereochemistry; Medicinal chemistry; Organic chemistry; Chemical engineering","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001892241,0.0002448954,0.0005916176,0.00003407991,0.0001332676,0.00002831492,0.0004301041,0.00007415871,0.00002124225],"category_scores_gemma":[0.0001952359,0.0001712601,0.000366798,0.0006696287,0.0009127554,0.0001217886,0.0001584109,0.0005791769,0.000003445208],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00025047,"about_ca_system_score_gemma":0.0001015455,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001868677,"about_ca_topic_score_gemma":0.000001214299,"domain_scores_codex":[0.9982661,0.00001667696,0.000531802,0.0002310734,0.0006367234,0.0003176162],"domain_scores_gemma":[0.9982462,0.0002457262,0.000722468,0.0003380511,0.0002247057,0.0002228494],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006698472,0.00004883823,0.007185477,0.00002218657,0.0002484914,0.000008959551,0.000360191,0.000957856,0.9873577,0.00001053272,0.003615413,0.0001173207],"study_design_scores_gemma":[0.0008960554,0.00003018717,0.003529111,0.00005082371,0.0001626604,0.0005626997,0.0003914227,0.006882916,0.9869341,0.000036428,0.0002443452,0.0002792425],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9975215,0.0001234148,0.001450204,0.000629258,0.00005078616,0.00007378642,0.00001491443,0.00004481136,0.00009130957],"genre_scores_gemma":[0.9967169,0.0002012742,0.00229625,0.0004816354,0.0002211039,0.000002830441,0.000009195775,0.00005136336,0.00001940908],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00592506,"threshold_uncertainty_score":0.6983783,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01141579122046625,"score_gpt":0.2262030957109812,"score_spread":0.2147873044905149,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}