{"id":"W1995631407","doi":"10.1002/chem.200400661","title":"New Insight into Solvent Effects on the Formal HOO. + HOO. Reaction","year":2005,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Free Radicals and Antioxidants","field":"Chemistry","cited_by":40,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada","funders":"Ministero dell’Istruzione, dell’Università e della Ricerca","keywords":"Chemistry; Radical; Reaction rate constant; Photochemistry; Chain termination; Acetonitrile; Reaction mechanism; Cyclohexane; Solvent; Hydrogen atom; Medicinal chemistry; Kinetics; Alkyl; Organic chemistry; Catalysis; Radical polymerization","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001136275,0.0002558161,0.0001574546,0.00005853245,0.0001115921,0.0002730875,0.0001995192,0.0001866442,0.002081312],"category_scores_gemma":[0.0002541782,0.00009160391,0.0001122978,0.00005510624,0.0002847095,0.0004820468,0.0001783077,0.0003699758,0.0004141913],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00015435,"about_ca_system_score_gemma":0.0001134119,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002461883,"about_ca_topic_score_gemma":0.0002526618,"domain_scores_codex":[0.9999318,0.00001099702,0.000003201048,0.00001621257,0.00001735928,0.00002035654],"domain_scores_gemma":[0.9998621,0.00007298985,0.00002970401,0.000006997126,0.00001611336,0.00001215149],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000122422,0.00002203058,0.0003402674,0.0002750919,0.000005277799,0.0001567891,0.00006880663,0.0001969031,0.9914631,0.0009886832,0.0001612391,0.006199342],"study_design_scores_gemma":[0.0000126779,0.0001372292,0.001243942,0.000008601692,0.000008510142,0.0001557025,0.00007976372,0.001667788,0.992282,0.0003132077,0.004082843,0.000007841719],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9726044,0.009235925,0.009288304,0.0004782206,0.0001165763,0.00003330865,0.0001786952,0.0001861862,0.007878304],"genre_scores_gemma":[0.9934146,0.003067685,0.001804926,0.0001037478,0.00003774749,0.00001585755,0.00009281912,0.00003064758,0.001431917],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002081312,"threshold_uncertainty_score":0.006962657,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009682239158344022,"score_gpt":0.2070086692933897,"score_spread":0.1973264301350456,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}