{"id":"W1995736296","doi":"10.1063/1.2929839","title":"Infrared spectroscopy of methanol-hexane liquid mixtures. I. Free OH present in minute quantities","year":2008,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Trois-Rivières","funders":"","keywords":"Mole fraction; Chemistry; Analytical Chemistry (journal); Methanol; Solubility; Attenuated total reflection; Infrared spectroscopy; Absorption band; Absorption (acoustics); Chromatography; Materials science; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002004203,0.0005887765,0.0002907171,0.0006516103,0.0001906186,0.0002708567,0.0003158751,0.0003702489,0.001858716],"category_scores_gemma":[0.0003465264,0.0001681877,0.0002419863,0.000557486,0.0002484268,0.0004236817,0.000279306,0.0006662056,0.0005304592],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001621265,"about_ca_system_score_gemma":0.00011234,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005923361,"about_ca_topic_score_gemma":0.0006212149,"domain_scores_codex":[0.9997234,0.00004228914,0.0000170095,0.00006616538,0.0001061574,0.00004494106],"domain_scores_gemma":[0.9997974,0.00007235234,0.00004735661,0.00001232541,0.00004847797,0.00002206761],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006893656,0.00001038667,0.0003100428,0.00005009491,0.000006995263,0.00003624361,0.00002302715,0.00004205391,0.9977149,0.00003022457,0.00002640931,0.00168068],"study_design_scores_gemma":[0.000006629352,0.000190511,0.00399297,0.00001696646,0.00002551295,0.0001369916,0.00007952056,0.0005804958,0.9930474,0.00005980454,0.001855565,0.000007555486],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9668128,0.009270604,0.01668667,0.0001696079,0.0001204672,0.00008176533,0.00102816,0.0003587073,0.005471196],"genre_scores_gemma":[0.9740597,0.005573167,0.0131257,0.000194514,0.0000602238,0.0001402175,0.001475941,0.0001337162,0.00523683],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001858716,"threshold_uncertainty_score":0.006218016,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0207502530698454,"score_gpt":0.2617972524913887,"score_spread":0.2410469994215433,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}