{"id":"W1995858368","doi":"10.1021/jo901616p","title":"How the Substituent at O-3 of <i>N</i>-Acetylglucosamine Impacts Glycosylation at O-4: A Comparative Study","year":2009,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"","keywords":"Chemistry; Trisaccharide; Disaccharide; N-Acetylglucosamine; Residue (chemistry); Glycosylation; Acceptor; Substituent; Reactivity (psychology); Stereochemistry; Organic chemistry; Enzyme; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002147347,0.0004861662,0.000163008,0.00007953212,0.00009014954,0.000224045,0.0002427556,0.0002482183,0.001133163],"category_scores_gemma":[0.0002281899,0.0001047677,0.0002347313,0.0001821454,0.0002404651,0.0002932819,0.0001493191,0.000340496,0.0003364564],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001532765,"about_ca_system_score_gemma":0.0001796925,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008670618,"about_ca_topic_score_gemma":0.0008434002,"domain_scores_codex":[0.9998941,0.00002123904,0.000004668625,0.00001542998,0.00002251035,0.0000419514],"domain_scores_gemma":[0.9998773,0.00003219267,0.00003553278,0.00001146166,0.00001924036,0.00002430897],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003117753,0.00002310438,0.0004219697,0.00003820462,0.00001012511,0.00008289508,0.00003791654,0.0001629853,0.9974067,0.00004666287,0.00001494438,0.001442682],"study_design_scores_gemma":[0.000007081376,0.000532616,0.002444155,0.00000411584,0.00001984103,0.0001343552,0.00003321908,0.0003258447,0.9957818,0.00002575788,0.0006839753,0.00000725985],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9976909,0.0002828072,0.0006632528,0.00001651115,0.000007389639,0.00001010002,0.00006381398,0.00001080649,0.001254458],"genre_scores_gemma":[0.9977955,0.0005010803,0.0007155018,0.00002746283,0.000003570289,0.000006110098,0.0001431677,0.000013782,0.0007938634],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001133163,"threshold_uncertainty_score":0.003790855,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02238577966593328,"score_gpt":0.2407928047472986,"score_spread":0.2184070250813654,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}