{"id":"W1995899918","doi":"10.1039/b514134f","title":"Reactivity of 4-vinylphenol radical cations in solution: implications for the biosynthesis of lignans","year":2005,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Plant-derived Lignans Synthesis and Bioactivity","field":"Biochemistry, Genetics and Molecular Biology","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada; Killam Trusts","keywords":"Chemistry; Reactivity (psychology); Radical ion; Flash photolysis; Photochemistry; Radical; Medicinal chemistry; Styrene; Alkyl; Hydroxyl radical; Reaction rate constant; Organic chemistry; Ion; Kinetics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002758191,0.0001655423,0.0002214235,0.00002877415,0.00008709128,0.000008076201,0.0003618719,0.0002179011,0.00003554583],"category_scores_gemma":[0.0002384596,0.0001386705,0.0001760172,0.0002099592,0.0002416977,0.000006568041,0.00008484088,0.00007931932,0.000001411456],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003942011,"about_ca_system_score_gemma":0.0002052217,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003714807,"about_ca_topic_score_gemma":0.00006780178,"domain_scores_codex":[0.9989375,0.00003964365,0.0003406214,0.0003359941,0.000108908,0.0002372835],"domain_scores_gemma":[0.9989076,0.0001056032,0.0002098131,0.0006259562,0.00009503091,0.00005598017],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003811755,0.0003178372,0.0006523758,0.00005181923,0.00007364481,2.294713e-7,0.00002745291,0.0000011886,0.9946494,0.0000321222,0.0002266647,0.003929151],"study_design_scores_gemma":[0.0002924168,0.00003226738,0.0034617,0.00002694618,0.00006270583,0.00001871466,0.00004867685,0.00005845087,0.9912614,0.00002493247,0.004560604,0.0001511374],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8067206,0.001878306,0.1841558,0.005342693,0.0000428725,0.0006042472,0.0005744711,0.00002054405,0.0006605355],"genre_scores_gemma":[0.9982029,0.0002351836,0.00119234,0.00004739216,0.000103664,0.00005863435,0.00008295953,0.0000217709,0.00005519506],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1914823,"threshold_uncertainty_score":0.565482,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.011610256968932,"score_gpt":0.2402124505208028,"score_spread":0.2286021935518708,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}