{"id":"W1995908963","doi":"10.1039/b806654j","title":"Trapping proton transfer intermediates in the disordered hydrogen-bonded network of cryogenic hydrofluoric acid solutions","year":2008,"lang":"en","type":"article","venue":"Physical Chemistry Chemical Physics","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Hydrofluoric acid; Chemistry; Ionization; Absorption spectroscopy; Absorption (acoustics); Hydrogen; Dissociation (chemistry); Aqueous solution; Infrared spectroscopy; Analytical Chemistry (journal); Physical chemistry; Chemical physics; Inorganic chemistry; Materials science; Ion; Organic chemistry; Optics; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.00008169049,0.0003848762,0.0005889824,0.00000723519,0.0001875905,0.00001327856,0.0005206225,0.0000803132,0.00005602466],"category_scores_gemma":[0.00001532997,0.0003054519,0.0004713017,0.0006090383,0.0005354355,0.0001128783,0.00008479563,0.0006405424,0.000008497024],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004779029,"about_ca_system_score_gemma":0.00006445235,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004026492,"about_ca_topic_score_gemma":4.41539e-7,"domain_scores_codex":[0.9979843,0.00003936106,0.0004510725,0.0004561289,0.000363138,0.0007059423],"domain_scores_gemma":[0.9991234,0.000230846,0.0001010782,0.0003884033,0.00005533162,0.0001009573],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005496067,0.00124324,0.00117775,0.00009207209,0.0001136818,0.000001739252,0.001127501,0.0000906284,0.9936367,0.001998144,0.000204268,0.0002593654],"study_design_scores_gemma":[0.0007137029,0.00002545927,0.00007994898,0.0000446705,0.00006021676,0.000001655111,0.0001407932,0.001166264,0.9450628,0.05227361,0.0001056751,0.0003252062],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9951,0.0001881005,0.0007954053,0.0001919402,0.00002038579,0.0003785579,0.00004579288,0.00004411477,0.003235699],"genre_scores_gemma":[0.9982156,0.0000210128,0.00003179348,0.00003289328,0.001215894,0.0003198771,0.0001171115,0.00003082608,0.00001499752],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05027546,"threshold_uncertainty_score":0.9999397,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01940291124081783,"score_gpt":0.238412215038315,"score_spread":0.2190093037974972,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}