{"id":"W1996000775","doi":"10.1021/ol901722q","title":"Gold-Catalyzed Synthesis of Carbon-Bridged Medium-Sized Rings","year":2009,"lang":"en","type":"article","venue":"Organic Letters","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":103,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Catalysis; Carbon fibers; Ketone; Quaternary carbon; Combinatorial chemistry; Organic chemistry; Enantioselective synthesis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001202205,0.0002108531,0.0003585712,0.00008098623,0.00004082888,0.00001963629,0.0003576129,0.0001145677,0.000628619],"category_scores_gemma":[0.0004323449,0.0001937492,0.0001429907,0.0002478228,0.00009336648,0.00008656452,0.00004696202,0.0002288413,0.00007243525],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002630355,"about_ca_system_score_gemma":0.0001082928,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001703142,"about_ca_topic_score_gemma":0.00001200298,"domain_scores_codex":[0.9986588,0.00001163275,0.0003694824,0.0003181304,0.0003204872,0.000321508],"domain_scores_gemma":[0.9987442,0.0002469489,0.0001941326,0.0006637739,0.00004002966,0.0001108653],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002093152,0.00006112926,0.0002267281,0.00003372975,0.00008313899,0.00001742771,0.000136863,8.162613e-7,0.9962671,0.00001273233,0.001668777,0.001470663],"study_design_scores_gemma":[0.0005269932,0.000003823385,0.001649183,0.00005437225,0.0001494826,0.00004938399,0.00007441937,0.00002114182,0.9966499,0.00001886838,0.0005804953,0.0002218867],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9847049,0.00003067836,0.0000319046,0.01058095,0.0001035017,0.00006035426,0.00001576932,0.0001688846,0.004303014],"genre_scores_gemma":[0.9988858,0.00001520645,0.0001411274,0.0004436437,0.0001950369,0.000008895843,0.00002001781,0.00003997741,0.000250363],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01418079,"threshold_uncertainty_score":0.7900864,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006370956955916274,"score_gpt":0.2040147090577235,"score_spread":0.1976437521018073,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}