{"id":"W1996052273","doi":"10.1081/ncn-200061905","title":"A DIRECT SYNTHESIS OF PYRROLOCYTOSINE FROM 5-IODOCYTOSINE","year":2005,"lang":"en","type":"article","venue":"Nucleosides Nucleotides & Nucleic Acids","topic":"DNA and Nucleic Acid Chemistry","field":"Biochemistry, Genetics and Molecular Biology","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Sonogashira coupling; Annulation; Combinatorial chemistry; Bicyclic molecule; Tandem; Nucleobase; Ring (chemistry); Chemistry; Yield (engineering); Pyrrole; Stereochemistry; Fluorescence; Organic chemistry; DNA; Catalysis; Palladium; Materials science; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002097701,0.0003322338,0.0002320972,0.00011675,0.0001683836,0.0001720857,0.0002774235,0.0003848488,0.001398249],"category_scores_gemma":[0.0002013986,0.0001567939,0.00017426,0.0001208511,0.0001527797,0.0002257067,0.0002890032,0.0005759806,0.0006025227],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001591516,"about_ca_system_score_gemma":0.0003646754,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005791017,"about_ca_topic_score_gemma":0.0010523,"domain_scores_codex":[0.9999058,0.00001199891,0.00001001887,0.00002907567,0.00002075892,0.00002229864],"domain_scores_gemma":[0.999903,0.00001589432,0.00001880276,0.00001845997,0.00002114158,0.00002268793],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004839858,0.00001327888,0.00005189157,0.00009399792,0.000005180817,0.0001799172,0.00004377617,0.000144568,0.9945047,0.0004326412,0.00004579157,0.004435797],"study_design_scores_gemma":[0.00001221982,0.0003077448,0.0002797781,0.000004529616,0.00001221968,0.0003453333,0.000009951714,0.0003062455,0.9927416,0.00004725193,0.005925666,0.000007466308],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9195695,0.005506015,0.06448215,0.0002532495,0.0002196787,0.0002650463,0.0005591858,0.0002982549,0.008846942],"genre_scores_gemma":[0.9529881,0.002348898,0.03993189,0.00005195873,0.00002200428,0.00005542838,0.0004200353,0.00003695116,0.004144683],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001398249,"threshold_uncertainty_score":0.004677594,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006700116598073868,"score_gpt":0.2210360409584967,"score_spread":0.2143359243604228,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}