{"id":"W1996062415","doi":"10.1021/ja021017f","title":"The Mandelamide Keto−Enol System in Aqueous Solution. Generation of the Enol by Hydration of Phenylcarbamoylcarbene","year":2002,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Enol; Mandelic acid; Keto–enol tautomerism; Aqueous solution; Reaction rate constant; Amide; Photochemistry; Flash photolysis; Equilibrium constant; Catalysis; Medicinal chemistry; Tautomer; Organic chemistry; Inorganic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001899484,0.000328448,0.000142793,0.0001367982,0.0001885319,0.0002237156,0.0002442992,0.000233711,0.001052097],"category_scores_gemma":[0.0002122392,0.0001415502,0.00008263873,0.0001168904,0.0001696922,0.00035541,0.0001769794,0.000446556,0.0002446313],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002725633,"about_ca_system_score_gemma":0.0002491938,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001238548,"about_ca_topic_score_gemma":0.001245444,"domain_scores_codex":[0.9998808,0.00001192911,0.000006528657,0.00004378289,0.00003671248,0.00002027181],"domain_scores_gemma":[0.9999447,0.0000134657,0.00001403444,0.000003474964,0.00001240334,0.0000119049],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004636149,0.000009816718,0.000135155,0.0000495987,0.000006170753,0.00002489032,0.00003320152,0.00009895084,0.9983162,0.00009610595,0.00002129002,0.001162165],"study_design_scores_gemma":[0.00001637522,0.0002505456,0.0008694831,0.000009742959,0.00001176947,0.00005730128,0.00005003296,0.00118219,0.9958389,0.00004933352,0.001657445,0.000006987245],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9930656,0.000953196,0.00277373,0.00006343736,0.00002735831,0.00004670678,0.0001965717,0.00005426014,0.002819061],"genre_scores_gemma":[0.9939193,0.001022192,0.002961063,0.00004167305,0.00001112111,0.00003809214,0.0004201675,0.00001153972,0.001574927],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001238548,"threshold_uncertainty_score":0.003519654,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01278646490819099,"score_gpt":0.215912386234567,"score_spread":0.203125921326376,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}