{"id":"W1996089397","doi":"10.1006/abio.1999.4437","title":"Quantitative Analysis of a Synthetic Peptide, NR58-3.14.3, in Serum by LC-MS with Inclusion of a Diastereomer as Internal Standard","year":2000,"lang":"en","type":"article","venue":"Analytical Biochemistry","topic":"Chemokine receptors and signaling","field":"Medicine","cited_by":22,"is_retracted":false,"has_abstract":false,"ca_institutions":"Nexen (Canada)","funders":"","keywords":"Diastereomer; Chemistry; Peptide; Chromatography; Stereochemistry; Combinatorial chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001582264,0.00115029,0.0005292857,0.0006473961,0.0005096207,0.0004025017,0.0005361883,0.0005905497,0.001101201],"category_scores_gemma":[0.001021716,0.0003205775,0.0003494774,0.0004564397,0.0006929035,0.000292257,0.0002816592,0.0007120822,0.0008522918],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007505739,"about_ca_system_score_gemma":0.001257478,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007807264,"about_ca_topic_score_gemma":0.001475281,"domain_scores_codex":[0.9987237,0.0002874419,0.00008158202,0.0003665115,0.0003719115,0.0001689038],"domain_scores_gemma":[0.9993268,0.0001883674,0.00008038043,0.0001081954,0.0001854467,0.0001107202],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003436013,0.00004676435,0.0002589228,0.00002907843,0.000009748288,0.00003368702,0.00002280338,0.0000563898,0.9973152,0.00006837106,0.00004820342,0.001767251],"study_design_scores_gemma":[0.00004698288,0.0004787174,0.001833464,0.000008578458,0.00002302182,0.0002228726,0.00001817742,0.001190022,0.9950642,0.0000822931,0.001023233,0.000008420345],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9246065,0.002741927,0.06450193,0.0003204827,0.0003179862,0.0004678151,0.001494169,0.0008238176,0.004725281],"genre_scores_gemma":[0.8321915,0.001795052,0.1524633,0.000538996,0.0001261149,0.001105528,0.003783913,0.0002112454,0.007784366],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001582264,"threshold_uncertainty_score":0.008367896,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006543987927697118,"score_gpt":0.2778321364340232,"score_spread":0.2712881485063261,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}