{"id":"W1996125390","doi":"10.1039/b712972f","title":"Rh-catalyzed P–P bond activation","year":2007,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":44,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Silylation; Catalysis; Chemistry; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002330108,0.0001110344,0.0001269254,0.00009759831,0.0001687717,0.00002584661,0.0008548211,0.0001359751,0.0003433873],"category_scores_gemma":[0.0003640469,0.0001171619,0.0001019589,0.0006163514,0.0001399659,0.0001152412,0.0002679042,0.0002825723,0.000172138],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001340155,"about_ca_system_score_gemma":0.0000295785,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002184929,"about_ca_topic_score_gemma":0.000005517308,"domain_scores_codex":[0.9990914,0.000007329629,0.0003148758,0.0001762613,0.0002069549,0.0002031469],"domain_scores_gemma":[0.9977242,0.0003765091,0.0001158111,0.001541809,0.000110312,0.0001313603],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001070777,0.0001977124,0.0003423861,0.00001189346,0.00004431493,3.790735e-7,0.0001674828,3.80755e-7,0.9673623,0.00529792,0.001217477,0.02534701],"study_design_scores_gemma":[0.0002595535,9.182496e-7,0.00008032164,0.000009389798,0.00002493459,0.00000315671,0.0002370253,0.0002119828,0.9357939,0.000441048,0.06279553,0.0001422624],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.4658539,0.0004068506,0.005817457,0.002012094,0.00002274945,0.00007821075,0.00001892369,0.0003524391,0.5254374],"genre_scores_gemma":[0.994749,0.00003923705,0.003363926,0.0001654035,0.00005463593,0.00001992066,0.0007993594,0.00001785541,0.0007907329],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.528895,"threshold_uncertainty_score":0.4777722,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02741390179004381,"score_gpt":0.2924181837166233,"score_spread":0.2650042819265794,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}