{"id":"W1996147332","doi":"10.1016/s0010-8545(02)00177-7","title":"Structure, chemical and photochemical reactivity and biological activity of some ruthenium amine nitrosyl complexes","year":2003,"lang":"en","type":"article","venue":"Coordination Chemistry Reviews","topic":"Nitric Oxide and Endothelin Effects","field":"Medicine","cited_by":315,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; Ruthenium; Aquation; Ligand (biochemistry); Cyclam; Photochemistry; Linkage isomerism; Electron paramagnetic resonance; Dissociation (chemistry); Reactivity (psychology); Amine gas treating; Electrochemistry; Redox; Cyclic voltammetry; Inorganic chemistry; Metal; Physical chemistry; Kinetics; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003189453,0.0002001274,0.0006492583,0.0000233133,0.00003331303,0.00000929684,0.00004947796,0.000178815,0.0001161193],"category_scores_gemma":[0.001164411,0.0001514945,0.00008087543,0.0001156015,0.0002212316,0.00007227685,0.00004249828,0.0002436081,0.000001897735],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003764757,"about_ca_system_score_gemma":0.00002534759,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000004106872,"about_ca_topic_score_gemma":8.851276e-8,"domain_scores_codex":[0.9990088,0.00007919075,0.0002887757,0.0003275736,0.0001256509,0.0001699577],"domain_scores_gemma":[0.9991788,0.0002006636,0.0001847357,0.0002264158,0.00006509713,0.0001443042],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007202054,0.0001072833,0.004563661,0.0006773752,0.00001651455,0.000002012425,0.0000111917,1.229535e-8,0.988834,0.00005057429,0.000238399,0.005427019],"study_design_scores_gemma":[0.001083957,0.00004523805,0.002234552,0.0001050271,0.000065147,0.0001603693,0.000006701344,0.00002890201,0.9886366,0.0005523321,0.006939345,0.0001417928],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9948811,0.003822816,0.00005265365,0.0001216765,0.00002138304,0.0004180056,0.00002149701,0.00002455857,0.000636331],"genre_scores_gemma":[0.9977964,0.001138847,0.0007303243,0.00007252446,0.00008285968,0.00002535986,0.00003563733,0.00001111805,0.0001068833],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006700946,"threshold_uncertainty_score":0.6177768,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03208115644172967,"score_gpt":0.2901775420180572,"score_spread":0.2580963855763276,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}