{"id":"W1996210158","doi":"10.1021/jo1016579","title":"Stereoselective Synthesis of 2-<i>C</i>-Branched (Acetylmethyl) Oligosaccharides and Glycoconjugates: Lewis Acid-Catalyzed Glycosylation from 1,2-Cyclopropaneacetylated Sugars","year":2011,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"Institute for Biological Sciences","funders":"National Natural Science Foundation of China; Chinese Academy of Sciences; National Science Foundation","keywords":"Chemistry; Lewis acids and bases; Glycosylation; Glycoconjugate; Stereoselectivity; Glycosyl donor; Monosaccharide; Catalysis; Glycosyl; Anomer; Stereochemistry; Selectivity; Acetal; Reactivity (psychology); Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001238431,0.0005365959,0.0002368363,0.0001607175,0.000123328,0.000191535,0.0002260829,0.0002380668,0.000779326],"category_scores_gemma":[0.00009073047,0.0001379508,0.0002452736,0.0003259332,0.0001119676,0.0002047807,0.0001998907,0.0003547382,0.0003310873],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000260058,"about_ca_system_score_gemma":0.0003746926,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000809852,"about_ca_topic_score_gemma":0.001488595,"domain_scores_codex":[0.9999102,0.00001234227,0.000005484866,0.00001263982,0.00001711824,0.00004209234],"domain_scores_gemma":[0.999963,0.00000296898,0.000008463026,0.000003651111,0.000007662708,0.0000142941],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005550122,0.00001931679,0.0001174172,0.00005155931,0.000008474244,0.0001365497,0.00002474673,0.0003014944,0.9957587,0.0005054137,0.00008786021,0.002932934],"study_design_scores_gemma":[0.00001091313,0.0001449868,0.0007372788,0.000003282717,0.00000884486,0.0001324401,0.00001307878,0.0004704177,0.9961988,0.00007922537,0.002192479,0.00000825131],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9786156,0.001333007,0.01165179,0.0000957119,0.00009424833,0.0001137294,0.0006896736,0.0001462602,0.007260039],"genre_scores_gemma":[0.9836362,0.001738418,0.01050072,0.00007541295,0.00001232415,0.00005102744,0.0005322727,0.00003853877,0.003415141],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000809852,"threshold_uncertainty_score":0.002607107,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01456045236192507,"score_gpt":0.1947920344231384,"score_spread":0.1802315820612134,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}