{"id":"W1996570771","doi":"10.1063/1.3669537","title":"Airfoil sampling of a pulsed Laval beam with tunable vacuum ultraviolet synchrotron ionization quadrupole mass spectrometry: Application to low-temperature kinetics and product detection","year":2011,"lang":"en","type":"article","venue":"Review of Scientific Instruments","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"National Nuclear Security Administration; National Science Council; National Aeronautics and Space Administration; U.S. Department of Energy","keywords":"Mass spectrometry; Materials science; Quadrupole mass analyzer; Quadrupole; Ionization; Synchrotron; Analytical Chemistry (journal); Kinetics; Atomic physics; Optics; Physics; Chemistry; Chromatography; Ion","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006585442,0.0005208329,0.0004714323,0.0003584925,0.0002298582,0.0005277786,0.0008980352,0.0005596111,0.0004308467],"category_scores_gemma":[0.0007592736,0.0002313275,0.0003002311,0.0003939451,0.0004707548,0.0006109643,0.000614296,0.0004523691,0.000196105],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005812756,"about_ca_system_score_gemma":0.0004592223,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007164215,"about_ca_topic_score_gemma":0.0006759276,"domain_scores_codex":[0.9994678,0.00007665303,0.00001983304,0.0001492561,0.0002523145,0.00003413012],"domain_scores_gemma":[0.9995436,0.0001303531,0.0001350518,0.00006476905,0.00009375595,0.00003247661],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000106517,0.00001628335,0.001542693,0.00006706196,0.00001012874,0.00003892465,0.00003137208,0.0002668465,0.9858892,0.000243596,0.00006086845,0.01172656],"study_design_scores_gemma":[0.00001481058,0.00019903,0.003769401,0.000005847224,0.00001355262,0.0002833826,0.00002272876,0.008426459,0.9847819,0.000106502,0.002358655,0.00001769458],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"methods","genre_scores_codex":[0.7493411,0.004435676,0.2423954,0.0001588253,0.00007351558,0.0002718483,0.0004382268,0.001062028,0.00182334],"genre_scores_gemma":[0.7584179,0.001611194,0.2379033,0.00008758804,0.00004835148,0.000253908,0.0003788622,0.00007631643,0.001222588],"genre_candidate":"methods","genre_consensus":null,"teacher_disagreement_score":0.0008980352,"threshold_uncertainty_score":0.004217505,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01054526442842446,"score_gpt":0.2409756630007363,"score_spread":0.2304303985723118,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}