{"id":"W1996939382","doi":"10.1021/om800856g","title":"Impact of the Linker on the Electronic and Luminescent Properties of Diboryl Compounds: Molecules with Two BMes<sub>2</sub> Groups and the Peculiar Behavior of 1,6-(BMes<sub>2</sub>)<sub>2</sub>pyrene","year":2008,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":65,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University; University of Toronto","funders":"","keywords":"Chemistry; Steric effects; Fluoride; Molecule; Ion; Electronic effect; Luminescence; Adduct; Naphthalene; Fluorescence; Linker; Crystallography; Photochemistry; Medicinal chemistry; Stereochemistry; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001369127,0.0003153759,0.0001667022,0.0001090193,0.0001115417,0.0002678485,0.0002264685,0.0003602645,0.001924554],"category_scores_gemma":[0.000288719,0.0001389475,0.00007798287,0.0001300737,0.000196318,0.0003272353,0.0001638833,0.0003018265,0.0002831967],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002225545,"about_ca_system_score_gemma":0.0001224586,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003279461,"about_ca_topic_score_gemma":0.0006638539,"domain_scores_codex":[0.9999133,0.00001509061,0.000006937728,0.00001891102,0.00001942323,0.0000263699],"domain_scores_gemma":[0.9998379,0.00005514702,0.00004801576,0.00001112337,0.00001883467,0.00002891459],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001527345,0.00001922203,0.0001085084,0.00004977806,0.000005214758,0.00002841841,0.00001608046,0.0001222163,0.9986381,0.00006468816,0.000009139957,0.00078592],"study_design_scores_gemma":[0.00001204873,0.0002239153,0.0007331791,0.000003603548,0.000009551862,0.00003219486,0.00001469197,0.0002119546,0.9983064,0.000008489576,0.000440832,0.000003286636],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9981266,0.0004494438,0.0004175874,0.00003535803,0.000006485502,0.00001057618,0.00006716119,0.00001660733,0.0008701202],"genre_scores_gemma":[0.9978216,0.0004382888,0.0009218487,0.00003765047,0.000002624315,0.00001594148,0.00009135999,0.00001249838,0.0006583112],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001924554,"threshold_uncertainty_score":0.006438255,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01008838485921793,"score_gpt":0.1999409586821873,"score_spread":0.1898525738229693,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}