{"id":"W1996939382","doi":"10.1021/om800856g","title":"Impact of the Linker on the Electronic and Luminescent Properties of Diboryl Compounds: Molecules with Two BMes<sub>2</sub> Groups and the Peculiar Behavior of 1,6-(BMes<sub>2</sub>)<sub>2</sub>pyrene","year":2008,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":65,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University; University of Toronto","funders":"","keywords":"Chemistry; Steric effects; Fluoride; Molecule; Ion; Electronic effect; Luminescence; Adduct; Naphthalene; Fluorescence; Linker; Crystallography; Photochemistry; Medicinal chemistry; Stereochemistry; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts"],"consensus_categories":[],"category_scores_codex":[0.000420024,0.0009104619,0.001179874,0.0001102871,0.0004236333,0.00007936832,0.0009507726,0.000351357,0.00004917412],"category_scores_gemma":[0.000205783,0.0004884147,0.0004777286,0.0007387072,0.00273788,0.0001762826,0.000453511,0.0009468555,0.000006385239],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002379224,"about_ca_system_score_gemma":0.0005761487,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005413971,"about_ca_topic_score_gemma":0.0000911165,"domain_scores_codex":[0.9961042,0.0001833003,0.001048169,0.000814591,0.0009732516,0.0008764588],"domain_scores_gemma":[0.9966428,0.0002588077,0.0009322335,0.001561178,0.0003680589,0.0002369193],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000525228,0.0007595146,0.01268577,0.0003713048,0.0005873866,0.00001038819,0.001035046,0.00001637862,0.9829772,0.0003061435,0.00008259092,0.0006430178],"study_design_scores_gemma":[0.003156639,0.0002452947,0.01748504,0.0002542785,0.0006626387,0.000221883,0.0004717392,0.00006459012,0.9767808,0.00005143736,0.00002528484,0.0005804063],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9959286,0.002454567,0.000009731432,0.0004602612,0.00005849681,0.0007244332,0.0001188214,0.00007244302,0.0001726285],"genre_scores_gemma":[0.9961838,0.003209624,0.00001303662,0.0001214292,0.0001412422,0.00008496758,0.00003672273,0.0001798819,0.00002936679],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006196463,"threshold_uncertainty_score":0.9999761,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01008838485921793,"score_gpt":0.1999409586821873,"score_spread":0.1898525738229693,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}