{"id":"W1997207387","doi":"10.1002/chem.200902188","title":"Triptycene‐Based Metal Salphens—Exploiting Intrinsic Molecular Porosity for Gas Storage","year":2009,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":105,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Triptycene; Porosity; Supramolecular chemistry; Materials science; Porous medium; Adsorption; Molecule; Nanotechnology; Chemical engineering; Hydrogen storage; Chemistry; Composite material; Physical chemistry; Organic chemistry; Engineering","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009098276,0.0001920209,0.0001569228,0.0001741914,0.0001423314,0.0003095386,0.0003779203,0.0002490978,0.001604788],"category_scores_gemma":[0.0001389501,0.0001329699,0.0001320687,0.0001549055,0.0002289749,0.0003537911,0.0003926145,0.0003027736,0.0004327672],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002672075,"about_ca_system_score_gemma":0.000139758,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002954063,"about_ca_topic_score_gemma":0.0007372739,"domain_scores_codex":[0.9999496,0.000006408418,0.000003219673,0.000008770913,0.00001429367,0.00001767667],"domain_scores_gemma":[0.9999409,0.00001133215,0.00001335378,0.00001344953,0.000006951437,0.00001411991],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001494967,0.00001861884,0.00007641999,0.0001445051,0.00001373328,0.0001005008,0.00003348691,0.0002349185,0.9919378,0.001758588,0.0002843243,0.005247647],"study_design_scores_gemma":[0.00002391597,0.0001235024,0.0003228761,0.000005069956,0.00001289565,0.000112716,0.0000183784,0.001391576,0.9932219,0.0001773881,0.004579876,0.000009944306],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9878529,0.0006786982,0.006259948,0.0001191811,0.00005041658,0.00002930649,0.0001778635,0.0002878564,0.004543856],"genre_scores_gemma":[0.9936853,0.0004136603,0.003335234,0.00006102605,0.000007965671,0.00002137395,0.0001408413,0.00003272229,0.002301809],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001604788,"threshold_uncertainty_score":0.00536859,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01927158683390518,"score_gpt":0.2351155446795279,"score_spread":0.2158439578456227,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}