{"id":"W1997207387","doi":"10.1002/chem.200902188","title":"Triptycene‐Based Metal Salphens—Exploiting Intrinsic Molecular Porosity for Gas Storage","year":2009,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":105,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Triptycene; Porosity; Supramolecular chemistry; Materials science; Porous medium; Adsorption; Molecule; Nanotechnology; Chemical engineering; Hydrogen storage; Chemistry; Composite material; Physical chemistry; Organic chemistry; Engineering","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0008137105,0.0003720209,0.000402488,0.00003536042,0.000446951,0.0002450335,0.000674082,0.0001122167,0.001867114],"category_scores_gemma":[0.0005836121,0.0003675568,0.0004598552,0.0001774138,0.00007470213,0.000107256,0.00005649151,0.0008436933,0.00004313968],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001320756,"about_ca_system_score_gemma":0.0001159786,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":3.732769e-7,"about_ca_topic_score_gemma":3.501209e-8,"domain_scores_codex":[0.9978173,0.00007846871,0.0007140975,0.0004864236,0.0003550878,0.000548561],"domain_scores_gemma":[0.9980934,0.0001169316,0.0005326635,0.0006501205,0.0001856296,0.0004212738],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005124827,0.0002012532,0.0000120768,0.00007107299,0.00006286202,0.000148974,0.00004345631,0.00006519898,0.9693251,0.00006180027,0.00123941,0.02871755],"study_design_scores_gemma":[0.001454124,0.00003504561,0.00008999608,0.0002046347,0.0002018391,0.0003534126,0.0001773242,0.001258594,0.9725357,0.0004643024,0.02270448,0.0005205893],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9465529,0.0006630631,0.03588779,0.001039443,0.00007909669,0.000115534,0.00004989502,0.000178863,0.0154334],"genre_scores_gemma":[0.9887143,0.00003433508,0.008860975,0.0004561492,0.001034833,0.000009289366,0.00005884024,0.00009033844,0.0007409005],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04216143,"threshold_uncertainty_score":0.9998776,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01927158683390518,"score_gpt":0.2351155446795279,"score_spread":0.2158439578456227,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}