{"id":"W1997374390","doi":"10.1021/ja034680s","title":"Cationic Organoscandium β-Diketiminato Chemistry:  Arene Exchange Kinetics in Solvent Separated Ion Pairs","year":2003,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":137,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Mesitylene; Cationic polymerization; Solvent; Dissociation (chemistry); Toluene; Photochemistry; Crystallography; Polymer chemistry; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002687985,0.000204248,0.0004679793,0.00001644758,0.0000591361,0.00003279286,0.0004876582,0.00008549901,0.003762887],"category_scores_gemma":[0.0002334017,0.0001520238,0.0005559575,0.0006622631,0.000247409,0.00004431284,0.00009251347,0.0004092206,0.000003590749],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005034698,"about_ca_system_score_gemma":0.0001184076,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002382382,"about_ca_topic_score_gemma":0.00000234024,"domain_scores_codex":[0.9984819,0.0000409276,0.0005502425,0.0002061781,0.000415131,0.0003056654],"domain_scores_gemma":[0.9984488,0.0001079749,0.0008129365,0.0003764992,0.000123282,0.0001304686],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001796802,0.0002712616,0.001452153,0.00005032732,0.0001102309,0.000002149776,0.000235475,0.00002055596,0.99534,0.000002759018,0.001519917,0.0009772093],"study_design_scores_gemma":[0.0004039678,0.00001562542,0.0007411513,0.00005390791,0.0001135867,0.00005120689,0.0006162171,0.0001111754,0.9809845,0.0001191589,0.0165961,0.000193419],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9966391,0.0004052145,0.0000320921,0.000819515,0.00004938595,0.00003184567,0.000008641823,0.00001238896,0.002001867],"genre_scores_gemma":[0.9982898,0.0002546654,0.0004128806,0.00015376,0.0001482162,0.000004934996,0.00000566,0.00002736926,0.0007027515],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01507618,"threshold_uncertainty_score":0.9971478,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01046252086885598,"score_gpt":0.2303454431023808,"score_spread":0.2198829222335248,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}