{"id":"W1998231701","doi":"10.1002/poc.453","title":"Preparation of the tricyclo[5.3.1.1<sup>3,9</sup>]dodeca‐1,5‐diyl dication: attempts to prepare a novel µ‐H cation","year":2001,"lang":"en","type":"article","venue":"Journal of Physical Organic Chemistry","topic":"Molecular spectroscopy and chirality","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Dication; Chemistry; Ab initio; Ab initio quantum chemistry methods; Ion; Computational chemistry; Medicinal chemistry; Molecule; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001650974,0.0002760279,0.0002267055,0.0001107952,0.000190973,0.0001819478,0.0003497447,0.0002426357,0.002765703],"category_scores_gemma":[0.0001987521,0.0001538369,0.0001275608,0.0001503622,0.0001479191,0.0002270819,0.0002095797,0.0003836005,0.0007082873],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002200532,"about_ca_system_score_gemma":0.0003298513,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002710117,"about_ca_topic_score_gemma":0.0007161163,"domain_scores_codex":[0.999913,0.00001072481,0.000008690155,0.00002150149,0.00001957507,0.00002650352],"domain_scores_gemma":[0.9999014,0.00001107064,0.00002126506,0.0000126427,0.00002063277,0.00003306261],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001873304,0.00002817586,0.0002519842,0.0002466591,0.00001364623,0.0002054361,0.00008300054,0.0007162736,0.9908338,0.001043532,0.000483919,0.005906216],"study_design_scores_gemma":[0.00007912394,0.0008842784,0.0008252082,0.00001323138,0.00001447538,0.0002630086,0.00004712471,0.001364416,0.9833613,0.0001623713,0.01296425,0.00002122866],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9830313,0.0009344822,0.007057318,0.0001573614,0.0001242379,0.0001410463,0.0007639946,0.0001106191,0.007679704],"genre_scores_gemma":[0.9786819,0.0007291769,0.0151016,0.0001041443,0.00001714845,0.00008595667,0.0008076766,0.00005932116,0.004413071],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002765703,"threshold_uncertainty_score":0.00925225,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008048100451777198,"score_gpt":0.2841541841268999,"score_spread":0.2761060836751227,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}