{"id":"W1998345117","doi":"10.1021/jp808253t","title":"Helix−Coil Transition of DNA Monitored by Pressure Perturbation Calorimetry","year":2009,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"DNA and Nucleic Acid Chemistry","field":"Biochemistry, Genetics and Molecular Biology","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Enthalpy; Aqueous solution; Calorimetry; Chemistry; Electromagnetic coil; Helix (gastropod); Heat capacity; Molar volume; Analytical Chemistry (journal); Thermodynamics; Crystallography; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001253376,0.0001337799,0.0001918081,0.000006376812,0.00004055672,0.000007676157,0.0002793362,0.0001185849,0.00001150267],"category_scores_gemma":[0.00004999257,0.00009521332,0.0001721202,0.00006408328,0.00008733168,0.000008091476,0.00001675337,0.0001854514,7.055309e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000009984851,"about_ca_system_score_gemma":0.00003824357,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000001239423,"about_ca_topic_score_gemma":2.018151e-8,"domain_scores_codex":[0.9992352,0.00002896713,0.0002543596,0.0001039654,0.0002454113,0.00013213],"domain_scores_gemma":[0.9992713,0.00002037453,0.0002603076,0.0002184598,0.0001523274,0.00007717291],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002517751,0.0002053168,0.000007782883,0.00004033271,0.00006663872,8.601668e-7,0.0001262293,0.0001046765,0.9949468,0.000001808452,0.003496133,0.0007516583],"study_design_scores_gemma":[0.000458989,0.0002499238,0.00009084308,0.00002874688,0.0001230644,0.00003041428,0.0001084386,0.0001393734,0.9963077,0.0001806912,0.00217994,0.0001018935],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9973356,0.0008791008,0.0003234215,0.0003319526,0.00002666182,0.00003172381,0.00003049816,0.000003889772,0.001037118],"genre_scores_gemma":[0.9984028,0.00007478548,0.00003259747,0.00007387665,0.0008575486,4.490458e-7,0.0000312835,0.00001001747,0.0005166263],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001360894,"threshold_uncertainty_score":0.3882686,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00314601544106211,"score_gpt":0.2153538338577489,"score_spread":0.2122078184166868,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}