{"id":"W1998355868","doi":"10.1016/s1387-3806(02)00525-0","title":"Scandium ionization mechanisms in H2–O2–N2 flames supported by calculated thermodynamic data","year":2002,"lang":"en","type":"article","venue":"International Journal of Mass Spectrometry","topic":"Catalytic Processes in Materials Science","field":"Materials Science","cited_by":4,"is_retracted":false,"has_abstract":false,"ca_institutions":"York University","funders":"National Institute of Standards and Technology; York University","keywords":"Chemistry; Scandium; Ionization; Computational chemistry; Ion; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.001254037,0.0001815462,0.0002987459,0.000564228,0.00004954737,0.0003028681,0.002546405,0.0000912063,0.005598701],"category_scores_gemma":[0.0005657498,0.0001611888,0.00005185606,0.000539343,0.0001147632,0.001172992,0.000292968,0.0001989948,0.0001282853],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003971337,"about_ca_system_score_gemma":0.0000926849,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004650905,"about_ca_topic_score_gemma":0.00001340122,"domain_scores_codex":[0.9971363,0.00008230694,0.0008235845,0.0003716246,0.001268544,0.0003176584],"domain_scores_gemma":[0.9983483,0.00009733612,0.0006796253,0.0004110532,0.0003606513,0.0001030432],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004927578,0.0001361185,0.000234909,0.000008022051,0.00002583255,0.0001670701,0.00007379123,0.0001723735,0.9969589,0.0006698453,0.001239453,0.0002644453],"study_design_scores_gemma":[0.001930852,0.0001900142,0.00206891,0.0001819678,0.00004469148,0.001252182,0.0001496876,0.04825248,0.9303067,0.01479077,0.00038241,0.0004492907],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9061227,0.0003419024,0.0879342,0.001443824,0.002972459,0.0001120913,0.0002176574,0.00004151156,0.0008136909],"genre_scores_gemma":[0.9915767,0.000132976,0.007662553,0.0001408153,0.0002062543,0.000001686379,0.00007279476,0.00002153429,0.0001847369],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08545398,"threshold_uncertainty_score":0.9953103,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01496645347899233,"score_gpt":0.2660474941876373,"score_spread":0.251081040708645,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}