{"id":"W1998413090","doi":"10.1002/chin.200330042","title":"Asymmetric Aldol Reactions Using a Fluorous Oxazolidinone Chiral Auxiliary.","year":2003,"lang":"en","type":"article","venue":"ChemInform","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"","keywords":"Chemistry; Aldol reaction; Chiral auxiliary; Combinatorial chemistry; Organic chemistry; Stereochemistry; Enantioselective synthesis; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001056204,0.0002845809,0.0002808229,0.00009303948,0.0002078436,0.00005600192,0.0002320569,0.0002690451,0.002977724],"category_scores_gemma":[0.0003229168,0.0002806861,0.0002729622,0.0007192399,0.0001209172,0.0002092449,0.00004574041,0.0003656095,0.00008427281],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001430896,"about_ca_system_score_gemma":0.00009891202,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001837273,"about_ca_topic_score_gemma":5.886325e-7,"domain_scores_codex":[0.998459,5.237175e-7,0.0004254939,0.0003084445,0.0002900599,0.000516466],"domain_scores_gemma":[0.9989165,0.00007204346,0.0001464964,0.000497521,0.0000938574,0.0002735573],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001709311,0.001916564,0.005887521,0.003383229,0.001453017,0.0002370019,0.0007980938,0.00003798652,0.8330012,0.02020494,0.05302247,0.07988706],"study_design_scores_gemma":[0.0004713028,0.000007290437,0.00002254624,0.00004758318,0.00008335556,0.0001301107,0.0002720827,0.0001931927,0.9022582,0.0005878719,0.09555856,0.0003679306],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.07586735,0.0002524232,0.0000278736,0.00001470387,0.00007040583,0.00004072495,0.00001408192,0.0001746503,0.9235378],"genre_scores_gemma":[0.9727141,0.00005242479,0.0004659381,0.00007936171,0.0002367377,0.00001534436,0.00004824456,0.00003546604,0.02635244],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.8971853,"threshold_uncertainty_score":0.9999645,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0196110882358708,"score_gpt":0.2484019991098542,"score_spread":0.2287909108739834,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}