{"id":"W1998464065","doi":"10.1016/s0022-1139(02)00224-5","title":"The coordination chemistry of (py)2BF2+ and related difluoroboron cations","year":2003,"lang":"en","type":"article","venue":"Journal of Fluorine Chemistry","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":10,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Manitoba; Brock University","funders":"","keywords":"Chemistry; Pyridine; Steric effects; Decomposition; Medicinal chemistry; Acetone; Boron; Ligand (biochemistry); Molecule; Stereochemistry; Photochemistry; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0009788543,0.0002159044,0.0003279836,0.00002382022,0.0002167708,0.00001994751,0.0003615691,0.0003570145,0.0009390268],"category_scores_gemma":[0.001547155,0.0001780327,0.000139955,0.0002659736,0.0003323011,0.00009196754,0.00007072738,0.001050993,0.000002708766],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001496078,"about_ca_system_score_gemma":0.0003252884,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002422359,"about_ca_topic_score_gemma":3.075449e-7,"domain_scores_codex":[0.9983208,0.00008864589,0.0009072119,0.0001817787,0.0002301179,0.0002714023],"domain_scores_gemma":[0.9975639,0.0006931375,0.000767297,0.0002905513,0.0004995606,0.0001855705],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000807258,0.0001870658,0.002979452,0.0002495492,0.0002570574,0.00001801707,0.00009811523,0.00006018765,0.9873329,0.0001984602,0.006484176,0.002054245],"study_design_scores_gemma":[0.001492209,0.00002337059,0.0003152306,0.00004729157,0.0002003588,0.0006383642,0.0002388911,0.00008487423,0.9403085,0.0004962586,0.05600903,0.0001456417],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9685169,0.004071452,0.00002128051,0.001891855,0.0005815998,0.00009535099,0.00001612118,0.00002135622,0.02478411],"genre_scores_gemma":[0.9831308,0.0008657425,0.0002024964,0.00003513088,0.0001885208,0.000005697724,0.000007993439,0.00001859154,0.01554503],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04952485,"threshold_uncertainty_score":0.9999743,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03094027684244897,"score_gpt":0.3595478596981873,"score_spread":0.3286075828557383,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}